<strong>Syntheses,Crystal Structures, and Magnetic Properties of Cobalt(II) Complexes with 1,1-Cyclohexanediacetic Acid</strong>

摘要
图/表
参考文献
相关文章 (15)

全文: PDF (743 KB) HTML (1 KB)
输出: BibTeX | EndNote (RIS)

摘要

Two new Co(II) coordination polymers, {[Co3(Hchda)2(chda)2(bpp)2(H2O)2]}n 1 and {[Co(chda)(bpe)(H2O)]•3H2O}n 2 (H2chda = 1,1-cyclohexanediacetic acid, bpp = 1,3-bis(4-pyridinyl)propane and bpe = 1,2-bis(4-pyridinyl)ethylene), were hydrothermally synthe- sized and then characterized by elemental analysis, IR spectroscopy, thermogravimetric analysis (TGA), and single-crystal X-ray diffraction. Complex 1 possesses an infinite metal-organic layer based on triply bridged linear trinuclear subunits and complex 2 exhibits a square (4,4) grid layer with dangling lateral arms resulting from eight-membered rings above and below the layer. In addition, magnetic properties of complexes 1 and 2 are also given.

	服务

	把本文推荐给朋友
	加入我的书架
	加入引用管理器
	E-mail Alert
	RSS
	作者相关文章
	鞠丰阳
	李云平
	李桂连
	刘广臻

关键词 ： 1,1-cyclohexanediacetic acid, hydrothermal synthesis, cobalt(II) complex, magnetic properties

Abstract：

Key words： 1,1-cyclohexanediacetic acid hydrothermal synthesis cobalt(II) complex magnetic properties

收稿日期: 2015-06-24 出版日期: 2016-03-11

基金资助:

This work was supported by the National Natural Science Foundation of China (No. 21571093), the Program for Science & Technology Innovation Talents in Universities of Henan Province (No. 14HASTIT017), the Program for Innovative Research Team (in Science and Technology) in University of Henan Province (No. 14IRTSTHN008), and the Foundation of Education Committee of Henan Province (No. 142300410301)

通讯作者: gzliuly@126.com E-mail: gzliuly@126.com

引用本文:

鞠丰阳;李云平;李桂连;刘广臻. Syntheses,Crystal Structures, and Magnetic Properties of Cobalt(II) Complexes with 1,1-Cyclohexanediacetic Acid[J]. 结构化学, 2016, 35(3): 404-412.
JU Feng-Yang;LI Yun-Ping;LI Gui-Lian;LIU Guang-Zhen. Syntheses,Crystal Structures, and Magnetic Properties of Cobalt(II) Complexes with 1,1-Cyclohexanediacetic Acid. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2016, 35(3): 404-412.

链接本文:

http://manu30.magtech.com.cn/jghx/CN/ 或 http://manu30.magtech.com.cn/jghx/CN/Y2016/V35/I3/404

REFERENCES
(1) Mullins, C. S.; Pecoraro, V. L. Reflections on small molecule manganese models that seek to mimic photosynthetic water oxidation chemistry. Coord. Chem. Rev. 2008, 252, 416–443.
(2) Deuss, P. J.; den Heeten, R.; Laan, W.; Kamer, P. C. J. Bioinspired catalyst design and artificial metalloenzymes. Chem. Eur. J. 2011, 17, 4680–4698.
(3) Hayashi, Y.; Santoro, S.; Azuma, Y.; Himo, F.; Ohshima, T.; Mashima, K. Enzyme-like catalysis via ternary complex mechanism: alkoxy-bridged dinuclear cobalt complex mediates chemoselective O-esterification over N-amidation, J. Am. Chem. Soc. 2013, 135, 6192–6199.
(4) Giri, S.; Biswas, S.; Drew, M. G. B.; Ghosh, A.; Saha, S. K. Structure and magnetic properties of a tetranuclear Cu(II) complex containing the 2-(pyridine-2-yliminomethyl)-phenol ligand. Inorg. Chim. Acta 2011, 368, 152–156.
(5) Stamatatos, T. C.; Boudalis, A. K.; Pringouri, K. V.; Raptopoulou, C. P.; Terzis, A.; Wolowska, J.; McInnes, E. J. L.; Perlepes, S. P. Mixed-valence cobalt(II/III) carboxylate clusters: CoII4CoIII2 and CoIICoIII2 complexes from the use of 2-(hydroxymethyl)pyridine. Eur. J. Inorg. Chem. 2007, 5098–5104.
(6) Reger, D. L.; Pascui, A. E.; Smith, M. D.; Jezierska, J.; Ozarowski, A. Dinuclear complexes containing linear M-F-M (M = Mn(II), Fe(II), Co(II), Ni(II), Cu(II), Zn(II), Cd(II)) bridges: trends in structures, antiferromagnetic superexchange interactions, and spectroscopic properties. Inorg. Chem. 2012, 51, 11820–11836.
(7) Yilmaz, V. T.; Hamamci, S.; Thӧne, C. Cobalt(II) complexes of 2-methanol-, 2,6-dimethanol- and 2-ethanolpyridines: syntheses, spectroscopic, thermal and structural characterizations of [Co2(μ-Cl)2(mpy)4]Cl2•H2O, [Co(dmpy)2]Cl2 and [Co(Cl)4](Hpyet)2 (mpy = 2-methanolpyridine; dmpy = 2,6-dimethanolpyridine and Hpyet = 2-ethanolpyridinium). Polyhedron 2004, 23, 841–848.
(8) Laine, T. V.; Klinga, M.; Leskelä, M. Synthesis and X-ray structures of new mononuclear and dinuclear diimine complexes of late transition metals. Eur. J. Inorg. Chem. 1999, 959–964.
(9) Darling, K.; Ouellette, W.; Prosvirin, A.; Walter, S.; Dunbar, K. R.; Zubieta, J. Hydrothermal synthesis and structures of materials of the M(II)/tetrazole/sulfate family (M(II) = Co, Ni; tetrazole = 3- and 4-pyridyltetrazole and pyrazinetetrazole). Polyhedron 2013, 58, 18–29.
(10) Pleus, R. J.; Waden, H.; Saak, W.; Haase, D.; Pohl, S. Preparation of the first sulfur-containing cobalt and nickel complexes stabilized by the macrocyclic cyclam ligand; observation of S-H bond activation. J. Chem. Soc., Dalton Trans. 1999, 2601–2610.
(11) Marsh, R. E.; Thewalt, U. Structure of racemic μ-amido-μ-hydroxy-bis[bis(ethylenediamine)cobalt(III)] tetranitrate hydrate. Inorg. Chem. 1971, 10, 1789–1795.
(12) Saunders, L. N.; Pratt, M. E.; Hann, S. E.; Dawe, L. N.; Decken, A.; Kerton, F. M.; Kozak, C. M. Structural variations in the coordination chemistry of amine-bis(phenolate) cobalt(II/III) complexes. Polyhedron 2012, 46, 53–65.
(13) Sharma, A. K.; Lloret, F.; Mukherjee, R. Phenolate- and acetate (both μ2-1,1 and μ2-1,3 modes)-bridged linear CoII3 and CoII2MnII trimers: magnetostructural studies. Inorg. Chem. 2013, 52, 4825–4833.
(14) Ma, L. F.; Li, B.; Wang, L. Y.; Fan, Y. T. Synthesis and crystal structure of a two-dimensional cobalt complex with 5-tert-butyl isophthalic acid. Chin. J. Struct. Chem. 2010, 29, 565–569.
(15) Hu, F. L.; Zou, H. H.; Zhao, X. B.; Mi, Y.; Luo, C. L.; Wang, Y. X. Second ligands-assisted structural variation of entangled coordination polymers with polycatenated or polythreaded features. CrystEngComm. 2013, 15, 1068–1076.
(16) Cao, Y. Y.; Chen, Y. M.; Li, L.; Gao, D. D.; Liu, W.; Hu, H. L.; Li, W.; Li, Y. H. A Co16 cluster and a 1-D Mn chain complex supported by benzohydroxamic acid. Dalton Trans. 2013, 42, 10912–10918.
(17) Liu, G. Z.; Li, X. L.; Xin, L. Y.; Wang, L. Y. Two topologically new trinodal cobalt(II) metal-organic frameworks characterized as a 1D metallic oxide and a 2D → 3D penetrated porous solid. CrystEngComm. 2012, 14, 5315–5321.
(18) Li, G. L.; Liu, G. Z.; Ma, L. F.; Xin, L. Y.; Li, X. L.; Wang, L. Y. Crystallographic determination of solid-state structural transformations in a dynamic metal-organic framework, Chem. Commun. 2014, 50, 2615–2617.
(19) He, J. R.; Wang, Y. L.; Bi, W. H.; Cao, R. Syntheses, structures and fluorescence of two Cd(II) complexes constructed from 1,1΄-cyclohexanediacetic acid. Chin. J. Inorg. Chem. 2006, 22, 1380–1386.
(20) Liu, T. F.; Lü, J.; Cao, R. Coordination polymers based on flexible ditopic carboxylate or nitrogen-donor ligands. CrystEngComm. 2010, 12, 660–670.
(21) Pigge, F. C. Losing control? ‘‘Design’’ of crystalline organic and metal-organic networks using conformationally flexible building blocks. CrystEngComm. 2011, 13, 1733–1748.
(22) Sheldrick, G. M. A Program for the Siemens Area Detector Absorption Correction. University of Göttingen, Germany 1997.
(23) Sheldrick, G. M. SHELXS-97, Program for the Solution of Crystal Structures. University of Gottingen, Göttingen, Germany 1997.
(24) Sheldrick, G. M. SHELXL-97, Program for Refinement of Crystal Structures. University of Gottingen, Göttingen, Germany 1997.
(25) Sun, H. L.; Wang, Z. M.; Gao, S. Synthesis, crystal structures, and magnetism of cobalt coordination polymers based on dicyanamide and pyrazine-dioxide derivatives. Inorg. Chem. 2005, 44, 2169–2176.
(26) Su, Z.; Fan, J.; Chen, M.; Okamura, T.; Sun, W. Y. Syntheses, characterization, and properties of three-dimensional pillared frameworks with entanglement. Cryst. Growth Des. 2011, 11, 1159–1169.
(27) Fisher, M. E. Magnetism in one-dimensional systems- the Heisenberg model for infinite spin. Am. J. Phys. 1964, 32, 343–346.
(28) Ma, B. Q.; Gao, S.; Yi, T.; Xu, G. X. One-dimensional coordination polymers [Co(acac)2pz]n and [Co(acac)2(4,4΄-bipy)]n (acac = acetylacetone, pz = pyrazine, bipy = 4,4΄-bipyridine): synthesis, structures and magnetic properties. Polyhedron 2001, 20, 1255–1261.