Crystal Structure, Thermal Behavior and Luminescence of a New Dimeric Manganese(II) Complex Constructed with 3-Carboxy-1-carboxymethyl-2-oxidopyridinium
王秀艳;王维;赵芳薇
a (Key Laboratory of Preparation and Applications of Environmental Friendly Materials, Jilin Normal University, Siping 136000, China)
b (Department of Chemistry, Jilin Normal University, Siping 136000, China)
Crystal Structure, Thermal Behavior and Luminescence of a New Dimeric Manganese(II) Complex Constructed with 3-Carboxy-1-carboxymethyl-2-oxidopyridinium
WANG Xiu-Yan;WANG Wei;ZHAO Fang-Wei
a (Key Laboratory of Preparation and Applications of Environmental Friendly Materials, Jilin Normal University, Siping 136000, China)
b (Department of Chemistry, Jilin Normal University, Siping 136000, China)
A new dimeric Mn(II) complex, namely, [Mn(L)(PIP)]2•H2O (1), was synthesized under hydrothermal condition (H2L = 3-carboxy-1-carboxymethyl-2-oxidopyridinium and PIP = 2-(pyridin-3-yl)-1H-imidazo[4,5-f][1,10]phenanthroline). It crystallizes in triclinic, space group P with a = 9.2037(13), b = 9.6794(13), c = 14.649(3) Å, α = 94.858(3), β = 94.928(3), γ = 114.468(2)o, V = 1172.9(3) Å3, Z = 1, C52H34Mn2N12O11, Mr = 1112.79, Dc = 1.575 g/cm3, F(000) = 568, μ(MoKa) = 0.618 mm-1, R = 0.0432 and wR = 0.1151. In 1, two L anions bridge two Mn(II) atoms to give a dimeric [Mn(L)(PIP)] unit with the Mn•••Mn distance of 3.009(2) Å. The two PIP ligands are located on both sides of the dimer, which provides suitable π-π stacking interactions between PIP ligands. By these π-π stacking interactions, adjacent dimers are extended into a two-dimensional supramolecular layer. Further, the strong N–H•••O hydrogen bond stabilizes the supramolecular layer structure of 1. Moreover, the thermal behavior and luminescent property of 1 have been studied.
A new dimeric Mn(II) complex, namely, [Mn(L)(PIP)]2•H2O (1), was synthesized under hydrothermal condition (H2L = 3-carboxy-1-carboxymethyl-2-oxidopyridinium and PIP = 2-(pyridin-3-yl)-1H-imidazo[4,5-f][1,10]phenanthroline). It crystallizes in triclinic, space group P with a = 9.2037(13), b = 9.6794(13), c = 14.649(3) Å, α = 94.858(3), β = 94.928(3), γ = 114.468(2)o, V = 1172.9(3) Å3, Z = 1, C52H34Mn2N12O11, Mr = 1112.79, Dc = 1.575 g/cm3, F(000) = 568, μ(MoKa) = 0.618 mm-1, R = 0.0432 and wR = 0.1151. In 1, two L anions bridge two Mn(II) atoms to give a dimeric [Mn(L)(PIP)] unit with the Mn•••Mn distance of 3.009(2) Å. The two PIP ligands are located on both sides of the dimer, which provides suitable π-π stacking interactions between PIP ligands. By these π-π stacking interactions, adjacent dimers are extended into a two-dimensional supramolecular layer. Further, the strong N–H•••O hydrogen bond stabilizes the supramolecular layer structure of 1. Moreover, the thermal behavior and luminescent property of 1 have been studied.
王秀艳;王维;赵芳薇. Crystal Structure, Thermal Behavior and Luminescence of a New Dimeric Manganese(II) Complex Constructed with 3-Carboxy-1-carboxymethyl-2-oxidopyridinium[J]. 结构化学, 2016, 35(3): 392-396.
WANG Xiu-Yan;WANG Wei;ZHAO Fang-Wei. Crystal Structure, Thermal Behavior and Luminescence of a New Dimeric Manganese(II) Complex Constructed with 3-Carboxy-1-carboxymethyl-2-oxidopyridinium. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2016, 35(3): 392-396.
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2016, Vol. 35 
