Synthesis,Crystal Structure and Luminescent Property of a Ag(Ι) Coordination Polymer with a 3D Sandwich-like Framework

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摘要

A new coordination polymer, {[Ag2(bpp)2(H2O)2]•bpdc•3H2O}n, derived from the ligand biphenyl-4,4΄-dicarboxylic acid (H2bpdc), has been obtained through a hydrothermal technique (bpp = 1,3-bis(4-pyridyl)propane). Its single-crystal structure has been characterized by single-crystal X-ray diffraction, powder XRD, FT-IR, TGA and elemental analysis techniques. The single-crystal X-ray diffraction reveals that complex 1 consists of 1D infinite [Ag(bpp)(H2O)]nn+ cationic chains, 2D anionic layer constructed by bpdc anions and free water which provide charge compensation in the crystal structure. The 1D infinite [Ag(bpp)(H2O)]nn+ cationic chains and 2D anionic layer are further stacked in -ABAB- fashion through intermolecular H-bonding to form a 3D sandwich-like framework. In addition, the luminescent property of complex 1 in the solid state at room temperature was investigated.

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	卢久富
	史娟
	郑楠
	郭小华
	葛红光

关键词 ： Ag(Ι) coordination polymer, crystal structure, luminescent property

Abstract：

Key words： Ag(Ι) coordination polymer crystal structure luminescent property

收稿日期: 2015-05-19 出版日期: 2016-01-29

基金资助:

This project was supported by the National Natural Science Foundation of China (No. 21373132) and the Foundation of Shaanxi university of technology (No. SLGKY15-36)

通讯作者: jiufulu@163.com E-mail: jiufulu@163.com

引用本文:

卢久富;史娟;郑楠;郭小华;葛红光. Synthesis,Crystal Structure and Luminescent Property of a Ag(Ι) Coordination Polymer with a 3D Sandwich-like Framework[J]. 结构化学, 2016, 35(2): 319-325.
LU Jiu-Fu;SHI Juan;ZHENG Nan;GUO Xiao-Hua;GE Hong-Guang. Synthesis,Crystal Structure and Luminescent Property of a Ag(Ι) Coordination Polymer with a 3D Sandwich-like Framework. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2016, 35(2): 319-325.

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http://manu30.magtech.com.cn/jghx/CN/ 或 http://manu30.magtech.com.cn/jghx/CN/Y2016/V35/I2/319

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