Synthesis of Calcium Hexaluminate from Waste Slag of Aluminum and Oyster Shell

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摘要

Waste aluminum slag and oyster shell were used as raw materials to synthesize calcium hexaluminate (CA6). The effects of different source materials of CaO and sintering temperature on the structures and properties of CA6 were investigated, respectively. The results show that compared to calcium oxide, oyster shell can lower the formation temperature of CA6, hence CA6 can be detected at 1300 ℃ by using oyster shell as the starting raw materials. Increasing the sintering temperature can promote the crystal growth. CA6 crystals show typical platelet shape, and its optimum sintering temperature falls in the 1450～1550 ℃ region. The bulk density is 1.54～1.83 g/cm3, the apparent porosity is 44.1～55.2% and the flexural strength is 10.8～25.3 MPa.

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	庄国鑫
	何亚军
	Malcolm Clark
	于岩

关键词 ： waste aluminum slag, calcium hexaluminate, oyster shell powder

Abstract：Waste aluminum slag and oyster shell were used as raw materials to synthesize calcium hexaluminate (CA6). The effects of different source materials of CaO and sintering temperature on the structures and properties of CA6 were investigated, respectively. The results show that compared to calcium oxide, oyster shell can lower the formation temperature of CA6, hence CA6 can be detected at 1300 ℃ by using oyster shell as the starting raw materials. Increasing the sintering temperature can promote the crystal growth. CA6 crystals show typical platelet shape, and its optimum sintering temperature falls in the 1450～1550 ℃ region. The bulk density is 1.54～1.83 g/cm3, the apparent porosity is 44.1～55.2% and the flexural strength is 10.8～25.3 MPa.

Key words： waste aluminum slag calcium hexaluminate oyster shell powder

收稿日期: 2015-05-19 出版日期: 2016-01-11

基金资助:

Supported by the National Natural Science Foundation of China (Nos. 51102047 and 51472050)

通讯作者: yuyan@fzu.edu.cn E-mail: yuyan@fzu.edu.cn

引用本文:

庄国鑫;何亚军;Malcolm Clark;于岩. Synthesis of Calcium Hexaluminate from Waste Slag of Aluminum and Oyster Shell[J]. 结构化学, 2016, 35(1): 157-165.
ZHUANG Guo-Xin;HE Ya-Jun;MALCOLM Clark;YU Yan. Synthesis of Calcium Hexaluminate from Waste Slag of Aluminum and Oyster Shell. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2016, 35(1): 157-165.

链接本文:

http://manu30.magtech.com.cn/jghx/CN/ 或 http://manu30.magtech.com.cn/jghx/CN/Y2016/V35/I1/157

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