Spectral, Thermal and Structural Studies of Two 3D Coordination Polymers Based on Tetracarboxylic Ligand

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摘要 Two new coordination polymers, [M6L3(DMA)3(H2O)] (M = Zn for 1, Cu for 2, L = tetrakis[3-(carboxyphenyl)oxamethyl]methane acid, DMA = N,N-dimethylacetamide) have been solvothermally synthesized. Single-crystal X-ray diffraction analysis reveals that compounds 1 and 2 are isostructural and crystallize in the trigonal space group R. The asymmetrical unit contains two metal ions, one L4 ligand and two coordinated DMA molecules. The metal ions are connected through six aromatic rings into a linear trimetallic zinc building unit. The whole structure is connected through tetrehedral ligand and the trimetallic building units to form a 4,6-connected framework of the toc topology. Compounds 1 and 2 are further studied by IR spectroscopy, thermogravimetric analyses and PXRD. The solid-state UV-Vis and photoluminescent properties of compounds 1 are also investigated.

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	梁丽丽
	徐磊
	李培
	陈飞剑
	薛洪宝

关键词 ： tetrakis[3-(carboxyphenyl)oxamethyl]methane acid, cupper complex, cadmium complex, luminescent property

Abstract：Two new coordination polymers, [M6L3(DMA)3(H2O)] (M = Zn for 1, Cu for 2, L = tetrakis[3-(carboxyphenyl)oxamethyl]methane acid, DMA = N,N-dimethylacetamide) have been solvothermally synthesized. Single-crystal X-ray diffraction analysis reveals that compounds 1 and 2 are isostructural and crystallize in the trigonal space group R. The asymmetrical unit contains two metal ions, one L4 ligand and two coordinated DMA molecules. The metal ions are connected through six aromatic rings into a linear trimetallic zinc building unit. The whole structure is connected through tetrehedral ligand and the trimetallic building units to form a 4,6-connected framework of the toc topology. Compounds 1 and 2 are further studied by IR spectroscopy, thermogravimetric analyses and PXRD. The solid-state UV-Vis and photoluminescent properties of compounds 1 are also investigated.

Key words： tetrakis[3-(carboxyphenyl)oxamethyl]methane acid cupper complex cadmium complex luminescent property

收稿日期: 2015-05-07 出版日期: 2016-01-11

基金资助:安徽省自然科学基金;安徽省优秀青年人才基金重点项目

通讯作者: hongbaoxueqhd@126.com E-mail: 1073557341@qq.com

引用本文:

梁丽丽;徐磊;李培;陈飞剑;薛洪宝. Spectral, Thermal and Structural Studies of Two 3D Coordination Polymers Based on Tetracarboxylic Ligand[J]. 结构化学, 2016, 35(1): 85-92.
LIANG Li-Li;XU Lei;LI Pei;CHEN Fei-Jian;XUE Hong-Bao. Spectral, Thermal and Structural Studies of Two 3D Coordination Polymers Based on Tetracarboxylic Ligand. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2016, 35(1): 85-92.

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http://manu30.magtech.com.cn/jghx/CN/ 或 http://manu30.magtech.com.cn/jghx/CN/Y2016/V35/I1/85

REFERENCES
(1)Yoon, M.; Srirambalaji, R.; Kim, K. Homochiral metal-organic frameworks for asymmetric heterogeneous catalysis. Chem. Rev. 2012, 112, 1196–1231.
(2)Liu, J.; Chen, L.; Cui, H.; Zhang, J.; Zhang, L.; Su, C. Applications of metal-organic frameworks in heterogeneous supramolecular catalysis. Chem. Soc. Rev. 2014, 43, 6011–6061.
(3)Dhakshinamoorthy, A.; Garcia, H. Metal-organic frameworks as solid catalysts for the synthesis of nitrogen-containing heterocycles. Chem. Soc. Rev. 2014, 43, 5750–5765.
(4)Allendorf, M. D.; Bauer, C. A.; Bhakta, R. K.; Houk, R. J. T. Luminescent metal-organic frameworks. Chem. Soc. Rev. 2009, 38, 1330–1352.
(5)Rieter, W. J.; Taylor, K. M. L.; Lin, W. Surface modification and functionalization of nanoscale metal-organic frameworks for controlled release and luminescence sensing. J. Am. Chem. Soc. 2007, 129, 9852–9853.
(6)Horcajada, P.; Serre, C.; Vallet-Regi, M.; Sebban, M.; Taulelle, F.; Férey, G. Metal-organic frameworks as efficient materials for drug delivery. Angew. Chem. Int. Ed. 2006, 45, 5974–5978.
(7)Horcajada, P.; Chalati, T.; Serre, C.; Gillet, B.; Sebrie, C.; Baati, T.; Eubank, J. F.; Heurtaux, D.; Clayette, P.; Kreuz, C.; Chang, J. S.; Hwang, Y. K.; Marsaud, V.; Bories, P. N.; Cynober, L.; Gil, S.; Ferey, G.; Couvreur, P.; Gref. R. Porous metal-organic framework nanoscale carriers as a potential platform for drug delivery and imaging. Nat. Mater. 2010, 9, 172–178.
(8)Sun, C. Y.; Qin, C.; Wang, C. G.; Su, Z. M.; Wang, S.; Wang, X. L.; Yang, G. S.; Shao, K. Z.; Lan, Y. Q.; Wang, E. B. Chiral nanoporous metal-organic frameworks with high porosity as materials for drug delivery. Adv. Mater. 2011, 23, 5629–5632.
(9)Rocca, J. D.; Liu, D.; Lin, W. B. Nanoscale metal-organic frameworks for biomedical imaging and drug delivery. Accounts of Chemical Research 2011, 44, 957–968.
(10)Kreno, L. E.; Leong, K.; Farha, O. K.; Allendorf, M.; Duyne, R. P. V.; Hupp, J. T. Metal-organic framework materials as chemical sensors. Chem. Rev. 2012, 112, 1105–1125.
(11)DeCoste, J. B.; Peterson, G. W. Metal-organic frameworks for air purification of toxic chemicals. Chem. Rev. 2014, 114, 5695–5727.
(12)Hu, Z.; Deibert, B. J.; Li, J. Luminescent metal-organic frameworks for chemical sensing and explosive detection. Chem. Soc. Rev. 2014, 43, 5815–5840.
(13)Liang, L.; Ge, G.; Tao, Z.; Zhang, L. Synthesis and crystal structure of a new complex constructed from a flexible tetrapyridyl ligand. Chin. J. Struct. Chem. 2012, 31, 1757–1761.
(14)Liang, L.; Ren, S.; Zhang, J.; Li, Y.; Du, H.; You, X. Two thermostable 3D homochiral metal-organic polymers with quartz topology. Cryst. Growth Des. 2010, 10, 1307–1311.
(15)Lu, Z.; Xing, H.; Sun, R.; Bai, J.; Zheng, B.; Li, Y. Water stable metal-organic framework evolutionally formed from a flexible multidentate ligand with acylamide groups for selective CO2 adsorption. Cryst. Growth Des. 2012, 12, 1081–1084.
(16)Schneemann, A.; Bon, V.; Schwedler, I.; Senkovska, I.; Kaskel, S.; Fischer, R. A. Flexible metal-organic frameworks. Chem. Soc. Rev. 2014, 43, 6062–6096.
(17)Liang, L.; Zhang, J.; Ren, S.; Ge, G.; Li, Y.; Du, H.; You, X. Rational synthesis of a microporous metal-organic framework with PtS topology using a semi-rigid tetrahedral linker. CrystEngComm. 2010, 12, 2008–2010.
(18)Liang, L.; Ren, S.; Zhang, J.; Li, Y.; Du, H.; You, X. Two unprecedented NLO-active coordination polymers constructed by a semi-rigid tetrahedral linker. Dalton Trans. 2010, 39, 7723–7726.
(19)Liang, L.; Ren, S.; Zhang, J.; Wang, J.; Li, Y.; Du, H.; You, X. A 3-dimensional coordination polymer with a fluorite structure constructed from a semi-rigid tetrahedral ligand. CrystEngComm. 2010, 12, 2669–2771.
(20)Yuan, W.; Li, H.; Guo, Z.; Cao, R. A cadmium coordination polymer with anatase topology constructed from a tetrapodal ligand: synthesis, crystal structures and luminescence. Inorg. Chem. Commun. 2011, 14, 366–369.
(21)Cao, C.; Wei, T. B.; Zhang, Q. S.; Lu, Y. Y.; Zhang, Y. M. Synthesis and crystal structures of 1D Cu coordination polymer based on tetrakis[3-(carboxyphenyl)oxamethyl]methane acid. Chin. J. Inorg. Chem. 2012, 28, 2530–2534.
(22)Kim, H.; Suh, M. P. Flexible eightfold interpenetrating diamondoid network generating 1D channels: selective binding with organic guests. Inorg. Chem. 2005, 44, 810–812.
(23)Sheldrick, G. M. SHELXS-97 and SHELXL-97, Program for X-ray Crystal Structure Solution. University of Göttingen, Göttingen, Germany 1997.
(24)Blatov, V. A. IUCr CompComm Newsletter 2006, 7, 4.
(25)Yam, V. V. W.; Lo, K. K. W. Luminescent polynuclear d10 metal complexes. Chem. Soc. Rev. 1999, 28, 323–334.
(26)Cui, Y.; Yue, Y.; Qian, G.; Chen, B. Luminescent metal-organic frameworks. Chem. Rev. 2012, 112, 1126–1162.