Synthesis of a Hexagonal Molecular Nickel-wheel

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The macrocyclic ligand -H2pyN2-O3ane (2) was readily prepared in a diluted condition in THF. The mixture of 2 and Ni(OTf)2 in DMF using Et4NOH as the base source gave a mononuclear square planar complex (Et4N)[Ni(OH)(-pyN2-O3ane)] (3). Addition of Fe(OTf)2 into the solution of 3 in DMF instantly generated a hexagonal molecular nickel-wheel 4 in 72% yield. Both 3 and 4 were characterized by X-ray crystallography on a MoKα radiation diffractometer (λ = 0.71073 Å): the crystal of 3 was grown in space group P212121 with a = 12.079(5), b = 15.099(6), c = 17.299(8) Å, V = 3160(2) Å3, Z = 4, Dc = 1.369 g/cm3, F(000) = 1384, C33H44N4NiO6, Mr = 651.43, μ = 0.665 cm-1, R = 0.0353, wR = 0.0668 for 4548 observed reflections with I > 2σ(I); 4 is in space group P21/n with a = 17.7416(17), b = 17.5490(17), c = 29.036(3) Å, β = 106.195(2)°, V = 8681.5(14) Å3, Z = 2, Dc = 1.352 g/cm3, F(000) = 3704, C170H190N22Ni6O40, Mr = 3533.70, μ = 719 cm-1, R = 0.0841 and wR = 0.2339 for 9371 observed reflections with I > 2σ(I).

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	谢兴昆
	张晓峰
	刘海雄
	王阳
	陈昌能
	黄德光

关键词 ： macrocyclic ligand, hydroxide, hexagonal, nickel-wheel

Abstract：

Key words： macrocyclic ligand hydroxide hexagonal nickel-wheel

收稿日期: 2015-03-23 出版日期: 2015-11-11

基金资助:

This investigation was granted by the National Natural Science Foundation of China (No. 21371171).

通讯作者: dhuang@fjirsm.ac.cn E-mail: dhuang@fjirsm.ac.cn

引用本文:

谢兴昆;张晓峰;刘海雄;王阳;陈昌能;黄德光. Synthesis of a Hexagonal Molecular Nickel-wheel[J]. 结构化学, 2015, 34(11): 1689-1696.
XIE Xing-Kun;ZHANG Xiao-Feng;LIU Hai-Xiong;WANG Yang;CHEN Chang-Neng;HUANG De-Guang. Synthesis of a Hexagonal Molecular Nickel-wheel. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2015, 34(11): 1689-1696.

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http://manu30.magtech.com.cn/jghx/CN/ 或 http://manu30.magtech.com.cn/jghx/CN/Y2015/V34/I11/1689

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