Syntheses,Structures, and Luminescent Properties of the ZnII and CdII 1-D Chain Polymers Assembled by Salicylhydroxamic Acid
高丹丹;高倩;陈砚美;李亚红;李武
a (Key Laboratory of Comprehensive and Highly Efficient Utilization of Salt Lake Resources,Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, Xining 810008, China)
b (College of Chemistry, Chemical Engineering and Materials Science,Soochow University, Suzhou 215123, China)
Synthesis, Structures, and Luminescent Properties of ZnII and CdII 1-D Chain Polymers Assembled by Salicylhydroxamic acid
a (Key Laboratory of Comprehensive and Highly Efficient Utilization of Salt Lake Resources,Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, Xining 810008, China)
b (College of Chemistry, Chemical Engineering and Materials Science,Soochow University, Suzhou 215123, China)
Two complexes of compositions [Zn(H2shi)(CH3COO)]n (1) and [Cd(H2shi)2(H2O)]n (2) (H3shi = salicylhydroxamic acid) have been prepared under solvothermal conditions. They are characterized by X-ray single-crystal diffraction, IR and elemental analysis. The crystal of 1 belongs to the tetragonal system, space group I41/a with a = 18.972(3), b = 18.972(3), c = 10.938(2) Å, V = 3937.1(1) Å3, C9H9NO5Zn, Mr = 276.54, Z = 16, Dc = 1.866 g/cm3, μ = 2.500 mm-1, F(000) = 2240, the final R = 0.0425 and wR = 0.123. The crystal of 2 belongs to the monoclinic system, space group P2/c with a = 16.647(3), b = 6.4577(1), c = 6.5623(1) Å, V = 702.4(2) Å3, C14H14Cd2N2O7, Mr = 434.68, Z = 2, Dc = 2.055 g/cm3, μ = 1.599 mm-1, F(000) = 432, the final R = 0.0211 and wR = 0.0761. They both possess 1-D polymeric chain structures. The luminescent properties of complexes 1 and 2 have been investigated.
Two complexes of compositions [Zn(H2shi)(CH3COO)]n (1) and [Cd(H2shi)2(H2O)]n (2) (H3shi = salicylhydroxamic acid) have been prepared under solvothermal conditions. They are characterized by X-ray single-crystal diffraction, IR and elemental analysis. The crystal of 1 belongs to the tetragonal system, space group I41/a with a = 18.972(3), b = 18.972(3), c = 10.938(2) Å, V = 3937.1(1) Å3, C9H9NO5Zn, Mr = 276.54, Z = 16, Dc = 1.866 g/cm3, μ = 2.500 mm-1, F(000) = 2240, the final R = 0.0425 and wR = 0.123. The crystal of 2 belongs to the monoclinic system, space group P2/c with a = 16.647(3), b = 6.4577(1), c = 6.5623(1) Å, V = 702.4(2) Å3, C14H14Cd2N2O7, Mr = 434.68, Z = 2, Dc = 2.055 g/cm3, μ = 1.599 mm-1, F(000) = 432, the final R = 0.0211 and wR = 0.0761. They both possess 1-D polymeric chain structures. The luminescent properties of complexes 1 and 2 have been investigated.
Supported by the National Natural Science Foundation of China (21272167, 51404234 and U140710123), a project Funded by the Priority Academic Program Development of Jiangsu Higher Education Institution and KLSLRC (KLSLRC-KF-13-HX-1)
高丹丹;高倩;陈砚美;李亚红;李武. Syntheses,Structures, and Luminescent Properties of the ZnII and CdII 1-D Chain Polymers Assembled by Salicylhydroxamic Acid[J]. 结构化学, 2015, 34(9): 1371-1378.
GAO Dan-Dan;GAO Qian;CHEN Yan-Mei;LI Ya-Hong;LI Wu. Synthesis, Structures, and Luminescent Properties of ZnII and CdII 1-D Chain Polymers Assembled by Salicylhydroxamic acid. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2015, 34(9): 1371-1378.
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2015, Vol. 34 
