Hydrothermal Synthesis, Crystal Structure, Thermal Stability and Photophysical Property of a Novel Zinc Complex with Mixed Ligands
闫丽;李传碧;崔迪;刘意瀛
1. 环境友好材料制备与应用教育部重点实验室
2. 吉林师范大学化学学院
Hydrothermal Synthesis, Crystal Structure, Thermal Stability and Photophysical Property of a Novel Zinc Complex with Mixed Ligands
YAN Li;LI Chuan-Bi;CUI Di;ZHANG Yi-Ying
Key Laboratory of Preparation and Applications of Environmental Friendly Materials, Ministry of Education, Department of Chemistry,
Jilin Normal University, Siping, Jilin 136000, China
摘要A novel metal-organic coordination complex [Zn(CHIP)(AIC)]n (1, CHIP = 2-(4- chlorophenyl)-1H-imidazo[4,5-f][1,10]phenanthroline, AIC = 5-amino-isophthalic acid) has been synthesized by hydrothermal reactions and characterized by elemental analysis, thermogravimetric (TG) analysis, infrared spectrum (IR) and single-crystal X-ray diffraction. Complex 1 crystallizes in monoclinic, space group C2/c with a = 18.259(5), b = 17.191(4), c = 16.371(4) Å, V = 4717(2) Å3, C27H16ClN5O4Zn, Mr = 575.29, Dc = 1.620 g/cm3, μ(MoKα) = 1.202 mm-1, F(000) = 2335, Z = 8, the final R = 0.032 and wR = 0.074 for 4723 observed reflections (I > 2σ(I)). Single-crystal X-ray diffraction reveals that 1 exhibits one-dimensional (1D) double chains, which are linked by H-bond intersections into a 2D structure. TG analysis shows clear weight loss due to the decomposition of different ligands.The luminescent properties for the ligand and complex 1 were also studied.
A novel metal-organic coordination complex [Zn(CHIP)(AIC)]n (1, CHIP = 2-(4- chlorophenyl)-1H-imidazo[4,5-f][1,10]phenanthroline, AIC = 5-amino-isophthalic acid) has been synthesized by hydrothermal reactions and characterized by elemental analysis, thermogravimetric (TG) analysis, infrared spectrum (IR) and single-crystal X-ray diffraction. Complex 1 crystallizes in monoclinic, space group C2/c with a = 18.259(5), b = 17.191(4), c = 16.371(4) Å, V = 4717(2) Å3, C27H16ClN5O4Zn, Mr = 575.29, Dc = 1.620 g/cm3, μ(MoKα) = 1.202 mm-1, F(000) = 2335, Z = 8, the final R = 0.032 and wR = 0.074 for 4723 observed reflections (I > 2σ(I)). Single-crystal X-ray diffraction reveals that 1 exhibits one-dimensional (1D) double chains, which are linked by H-bond intersections into a 2D structure. TG analysis shows clear weight loss due to the decomposition of different ligands.The luminescent properties for the ligand and complex 1 were also studied.
The project was supported by the Science Development Project of Jilin Province (20130522071JH)
通讯作者:
闫丽
E-mail: yanli820618@163.com
引用本文:
闫丽;李传碧;崔迪;刘意瀛. Hydrothermal Synthesis, Crystal Structure, Thermal Stability and Photophysical Property of a Novel Zinc Complex with Mixed Ligands[J]. 结构化学, 2015, 34(2): 221-226.
YAN Li;LI Chuan-Bi;CUI Di;ZHANG Yi-Ying. Hydrothermal Synthesis, Crystal Structure, Thermal Stability and Photophysical Property of a Novel Zinc Complex with Mixed Ligands. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2015, 34(2): 221-226.
REFERENCES
(1)Xu, J.; Su, Z.; Chen, M. S.; Chen, S. S.; Sun, W. Y. New metal complexes with 5-(1H-imidazol-4-ylmethyl)aminoisophthalic acid: syntheses, structures, electrochemistry and electrocatalysis. Inorg. Chim. Acta 2009, 362, 4002–4008.
(2)Li, H.; Eddaoudi, M.; Keeffe, M. O.; Yaghi, O. M. Design and synthesis of an exceptionally stable and highly porous metal-organic framework. Nature 1999, 402, 276–279.
(3)Swavey, S.; Swavey, R. Dinuclear and polynuclear lanthanide coordination complexes containing polyazine ligands: synthesis and luminescent properties. Coord. Chem. Rev. 2009, 253, 2627–2638.
(4)Kepert, C. J.; Rosseinsky, M. J. A porous chiral framework of coordinated 1,3,5-benzenetricarboxylate: quadruple interpenetration of the (10,3)-a network. Chem. Commun. 1998, 1, 31–32.
(5)Zhang, J. P.; Chen, X. M. Crystal engineering of binary metal imidazolate and triazolate frameworks. Chem. Comm. 2006, 16, 1689–1699.
(6)Liu, B.; Guo, J.; Zhou, S.; Wang, Q. W.; Li, X. M.; Li C. B. Synthesis and crystal structure of a two-dimensional coordination polymer constructed by thiophene-2,5-dicarboxylic acid and 1,4-bis(imidazol-1-yl)-butane. Chin. J. Struct. Chem. 2013, 32, 199–204.
(7)Miller, J. S.; Gatteschi, D. Molecule-based magnets. Chem. Soc. Rev. 2011, 40, 3065–3066.
(8)Zhang, Q. L.; Liu, J. H.; Ren, X. Z.; Xu, H.; Huang, Y.; Liu, J. Z.; Ji, L. N. A functionalized cobalt(III) mixed-polypyridyl complex as a newly designed DNA molecular light switch. J. Inorg. Biochem. 2003, 95, 194–198.
(9)Sheldrick, G. M. SHELXS 97, Program for the Solution of Crystal Structure (University of Göttingen, Germany 1997).
(10)Sheldrick, G. M. SHELXL 97, Program for the Refinement of Crystal Structure (University of Göttingen, Germany 1997).
(11)Croitor, L.; Coropceanu, E. B.; Siminel, A. V.; Botoshansky, M. M.; Fonari, M. S. Synthesis, structures, and luminescence properties of mixed ligand Cd(II) and Zn(II) coordination compounds mediated by 1,2-bis(4-pyridyl)ethane. Inorg. Chim. Acta 2011, 370, 411–419.
(12)Yang, F.; Ren, Y. X.; Li, D. S.; Fu, F.; Qi, G. C.; Wang, Y. Y. 1D zigzag chain and 0D monomer Cd(II)/Zn(II) compounds based on flexible phenylenediacetic ligand: synthesis, crystal structures and fluorescent properties. J. Mol. Struct. 2008, 892, 283–288.
(13)Zhu, S.; Sun, S. M.; Li, Y. Z.; Wu, B. L.; Zhang, H. Y. Dinuclear Zn(II) and Hg(II) complexes of an angular dipyridyl ligand: syntheses, crystal structures, and properties. J. Coord. Chem. 2010, 63, 4236–4244.
(14)Song, J. F.; Zhou, R. S.; Hu, T. P.; Chen, Z.; Wang, B. B. Three new coordination complexes based on 2-methyl-4,5-imidazoledicarboxylic acid varying from zero- to two-dimensionality. J. Coord. Chem. 2010, 63, 4201–4214.
(15)Khan, T. A.; Ghani, S. S.; Naseem, S. Interaction of Co(II), Ni(II), Cu(II), and Zn(II) with 12- and 14-memberedmacrocycles containing O2N2 donors. J. Coord. Chem. 2010, 63, 4411–4420.
(16)Liu, Y. Y.; Ma, J. F.; Yang, J.; Su, Z. M. Syntheses and characterization of six coordination polymers of zinc(II) and cobalt(II) with 1,3,5-benzenetricarboxylate anion and bis(imidazole) ligands. Inorg. Chem. 2007, 46, 3027–3037.
(17)Duan, Y. L.; Lin, Z. N.; Stips, T.; Dehnen, S. Solvothermal synthesis of new luminescent zinc(II) coordination polymers with one-dimensional homochiral structures. Z. Anorg. Allg. Chem. 2010, 636, 2535–2538.
(18)Wang, R. M.; Zhang, J.; Li, L. J. A 2D metal-organic framework with a flexible cyclohexane-1,2,5,6-tetracarboxylic acid ligand: synthesis, characterization and photoluminescent property. J. Mol. Struct. 2010, 970, 14–18.
(19)Zhu, H. L.; Zheng, Y. Q. Three new butane-1,2,3,4-tetracarboxylato-bridged coordination polymers: syntheses, crystal structures and characterization. J. Mol. Struct. 2010, 970, 27–35.
(20)Pochodylo, A. L.; LaDuca, R. L. Substituent dependent dimensionality in luminescent zinc isophthalate coordination polymers containing bis(3-pyridylmethyl)piperazine. Z. Anorg. Allg. Chem. 2010, 636, 2568–2573.
(21)Zhang, L. P.; Ma, J. F.; Yang, J.; Liu, Y. Y.; Wei, G. H. 1D, 2D, and 3D metal-organic frameworks based on bis(imidazole) ligands and polycarboxylates: syntheses, structures, and photoluminescent properties. Crystal Growth & Design 2009, 9, 4660–4673.
(22)Xu, G. J.; Zhao, Y. H.; Shao, K. Z.; Xu, Y. H.; Wang, X. L.; Su, Z. M.; Yan, L. K. Syntheses and characterization of two coordination polymers constructed by the ligand 3,5-bis(pyridin-4-ylmethoxy)benzoic acid. Z. Anorg. Allg. Chem. 2009, 635, 2671–2675.
2015, Vol. 34 
