Syntheses, Structures, and Photoluminescent Properties of Two 2D Coordination Polymers Base on 1, 3-Di (2, 4-dicarboxyphenyl) Benzene and 1, 3-Di (4-pyridyl) propane
王记江;苏永超;高楼军
1. 延安大学化学与化工学院
2. 延安大学
Syntheses, Structures, and Photoluminescent Properties of Two 2D Coordination Polymers Base on 1, 3-Di (2, 4-dicarboxyphenyl) Benzene and 1, 3-Di (4-pyridyl) propane
WANG Ji-Jiang;SU Yong-Chao;GAO Lou-Jun
Department of Chemistry and Chemical Engineering, Shaanxi Key Laboratory of Chemical Reaction Engineering, Yan’an University, Yan’an 716000, China
摘要Two new 2D coordination polymers, [Zn(HL)(Hbpp)]n (1) and [Cd(HL)(Hbpp)(H2O)]n (2) (H4L = 1,3-di(2,4-dicarboxyphenyl) benzene, bpp = 1,3-di(4-pyridyl)propane), have been hydrothermally synthesized and characterized by single-crystal X-ray diffraction analysis, elemental analysis, TGA and IR spectroscopy. Complex 1 crystallizes in monoclinic, space group P21/n, with a = 13.1031(6), b = 14.7315(7), c = 15.0041(7) Å, β = 91.202(1)°, V = 2895.6(2) Å3, Dc = 1.532 g/cm3, Mr = 667.97, F(000) = 1376.0, μ = 0.909 mm–1, Z = 4, the final R = 0.0481 and wR = 0.1304 for 7027 observed reflections with I > 2σ(I). Complex 2 also belongs to the monoclinic space group P21/n, with a = 13.6326(4), b = 14.6432(4), c = 14.9395(5) Å, β = 93.132(1)º, V = 2977.84(16) Å3, Dc = 1.613 g/cm3, Mr = 1445.98, F(000) = 733.0, μ = 0.794 mm–1, Z = 2, the final R = 0.0283 and wR = 0.0784 for 7230 observed reflections with I > 2σ(I). Both complexes 1 and 2 form 2D net structures, which are further linked to form 3D supramolecular net structures via intermolecular hydrogen bonds and aromatic π-π stacking interactions.
Abstract：Two new 2D coordination polymers, [Zn(HL)(Hbpp)]n (1) and [Cd(HL)(Hbpp)(H2O)]n (2) (H4L = 1,3-di(2,4-dicarboxyphenyl) benzene, bpp = 1,3-di(4-pyridyl)propane), have been hydrothermally synthesized and characterized by single-crystal X-ray diffraction analysis, elemental analysis, TGA and IR spectroscopy. Complex 1 crystallizes in monoclinic, space group P21/n, with a = 13.1031(6), b = 14.7315(7), c = 15.0041(7) Å, β = 91.202(1)°, V = 2895.6(2) Å3, Dc = 1.532 g/cm3, Mr = 667.97, F(000) = 1376.0, μ = 0.909 mm–1, Z = 4, the final R = 0.0481 and wR = 0.1304 for 7027 observed reflections with I > 2σ(I). Complex 2 also belongs to the monoclinic space group P21/n, with a = 13.6326(4), b = 14.6432(4), c = 14.9395(5) Å, β = 93.132(1)º, V = 2977.84(16) Å3, Dc = 1.613 g/cm3, Mr = 1445.98, F(000) = 733.0, μ = 0.794 mm–1, Z = 2, the final R = 0.0283 and wR = 0.0784 for 7230 observed reflections with I > 2σ(I). Both complexes 1 and 2 form 2D net structures, which are further linked to form 3D supramolecular net structures via intermolecular hydrogen bonds and aromatic π-π stacking interactions.
基金资助:Supported by the National Natural Science Foundation of China (No. 21373178) , the Open Foundation of Key Laboratory of Synthetic and NaturalFunctional Molecule Chemistry of Ministry of Education (338080043), and the Natural Scientific Research Foundation of Shaanxi Provincial Education Office of China (No. 13JS124)
通讯作者:
高楼军
E-mail: glj@yau.edu.cn
引用本文:
王记江;苏永超;高楼军. Syntheses, Structures, and Photoluminescent Properties of Two 2D Coordination Polymers Base on 1, 3-Di (2, 4-dicarboxyphenyl) Benzene and 1, 3-Di (4-pyridyl) propane[J]. 结构化学, 2015, 34(2): 241-247.
WANG Ji-Jiang;SU Yong-Chao;GAO Lou-Jun. Syntheses, Structures, and Photoluminescent Properties of Two 2D Coordination Polymers Base on 1, 3-Di (2, 4-dicarboxyphenyl) Benzene and 1, 3-Di (4-pyridyl) propane. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2015, 34(2): 241-247.
REFERENCES
(1)Lee, J.; Farha, O. K.; Roberts, J.; Scheidt, K. A.; Nguyen, S. T.; Hupp, J. T. Metal-organic framework materials as catalysts. Chem. Soc. Rev. 2009, 38, 1450–1459.
(2)Cui, G. H.; He, C. H.; Jiao, C. H.; Geng, J. C.; Blatov, V. A. Two metal-organic frameworks with unique high-connected binodal network topologies:
synthesis, structures, and catalytic properties. CrystEngComm. 2012, 14, 4210–4216.
(3)Du, M.; Chen, Y. Q.; Bu, X. H. Highlights of recent advances in functional coordination polymers made in China. Chin. Sci. Bull. 2011, 56, 2297–2299.
(4)Zhang, Y.; Zhang, W.; Li, S. H.; Ye, Q.; Cai, H. L.; Deng, F.; Xiong, R. G.; Huang, S. D. Ferroelectricity induced by ordering of twisting motion in a molecular rotor. J. Am. Chem. Soc. 2012, 134, 11044−11049.
(5)Kurmoo, M. Magnetic metal-organic frameworks. Chem. Soc. Rev. 2009, 38, 1353–1379.
(6)Li, L. J.; Wang, X. L.; Shao, K. Z.; Su, Z. M. A novel luminescent 3D metal-organic framework possessing 3-fold interpenetrating (3, 5)-connected net. Inorg. Chem. Commun. 2012, 26, 42–45.
(7)Guo, J.; Yang, J.; Liu, Y. Y.; Ma, J. F. Two novel 3D metal-organic frameworks based on two tetrahedral ligands: syntheses, structures, photoluminescence and photocatalytic properties. CrystEngComm. 2012, 14, 6609–6617.
(8)Allendorf, M. D.; Bauer, C. A.; Bhakta, R. K.; Houk, R. J. T. Luminescent metal-organic frameworks. Chem. Soc. Rev. 2009, 38, 1330−1352.
(9)McKinlay, A. C.; Xiao, B.; Wragg, D. S.; Wheatley, P. S.; Megson, I. L.; Morris, R. E. Exceptional behavior over the whole adsorption-storage-delivery cycle for NO in porous metal organic frameworks. J. Am. Chem. Soc. 2008, 130, 10440–10444.
(10)Lin, Z. J.; Huang, Y. B.; Liu, T. F.; Li, X. Y.; Cao, R. Construction of a polyhedral metal-organic framework via a flexible octacarboxylate ligand for gas adsorption and separation. Inorg. Chem. 2013, 52, 3127–3132.
(11)Ye, B. H.; Tong, M. L.; Chen, X. M. Meta-organic molecular architectures with 2,2΄-bipyridyl-like and carboxylate ligands. Coord. Chem. Rev. 2005, 249(5-6), 545–565.
(12)Hu S.; Chen, J. C.; Tong, M. L.; Wang, B.; Yan, Y. X.; Batten, S. R. Cu2+-Mediated dehydrogenative coupling and hydroxylation of a N-heterocycle ligand: from generating a new tetratopic ligand to designed assembly of three-dimensional copper(I) coordination polymers. Angew. Chem. Int. Ed. 2005, 44, 5471–5475.
(13)Sun, D. F.; Collins D. J.; Ke, Y. X. Construction of open metal-organic frameworks based on predesigned carboxylate isomers: from achiral to chiral to chiral nets. Chem. Eur. J. 2006, 3768–3776.
(14)Wen, L. L.; Zhao, J. B.; Lv, K.; Wu, Y. H.; Deng, K. J.; Leng, X. K.; Li, D. F. Visible-light-driven photocatalysts of metal-organic frameworks derived from multi-carboxylic acid and imidazole-based spacer. Cryst. Growth. Des. 2012, 12, 1603–1612.
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2015, Vol. 34 
