(2) A comprehensive review on polyoxometalates has been given by Prof. Hill, et. al. Chem. Rev. 1998, 98, 1–389.
(4) Wang, X.; Liu, L.; Zhang G.; Jacobson, A. J. An extended chain structure formed by covalently linking polyoxovanadate cages with tetrahedral six rings. Chem. Commun. 2001, 2472–2473.
(5) Muller, A.; Krickemeyer, E.; Bogge, H.; Schmidtmann, M.; Peters, F.; Menke, C.; Meyer, J.An unusual polyoxomolybdate: giant wheels linked to chains. Angew. Chem. Int. Ed. Engl. 1997, 36, 484–486.
(6) Hagrman, P. J.; Hagrman, D.; Zubieta, J. Organic-inorganic hybrid materials: from "simple" coordination polymers to organodiamine-templated molybdenum oxide. Angew. Chem. Int. Ed. Engl. 1999, 38, 2639–2684.
(8) Nohra, B.; Moll, H. E.; Albelo, L. M. R.; Mialane, P.; Marrot, J.; Mellot- Draznieks, C.; O’Keeffe, M.; Biboum, R. N.; Lemaire, J.; Keita, B.; Nadjo, L.; Dolbecq, A. Polyoxometalate-based metal organic frameworks (POMOFs): structural trends, energetics, and high electrocatalytic efficiency for hydrogen evolution reaction. J. Am. Chem. Soc. 2011, 133, 13364–13374.
(9) Yang, W.; Lu, C.; Lin, X.; Zhuang H.; Huang, J. (NH4)15[H3Mo57V6(NO)6O189(H2O)12(VO)6]·60H2O: new nanocompound obtained by chemical embellishment of {M57V6}. Inorg. Chem. 2000, 39, 2706–2707.
(10) Yang, W.; Lu, C.; Lin, X.; Zhuang, H. A novel acetated 54-member crown-shaped polyoxomolybdate with unprecedented structural features: Na26[{Na(H2O)2}6({μ3-OH)4MoV20MoVI34O164(μ2-CH3COO)4}]·120H2O. Chem Commun. 2000 1623-1624; (b) Yang, W.; Lu, C.; Lin, X.; Zhuang, H. Novel acetate polyoxomolybdate “host” accommodating a zigzag-chainlike “guest” of five edge-shared sodium cations: Na21{[Na5(H2O)14][Mo46O134(OH)10(CH3COO)4]}·CH3COONa·≈95H2O. Inorg. Chem. 2002, 41, 452–454.
(11) Yang, W.; Lu, C.; Zhan X.; Zhuang, H. Hydrothermal synthesis of the first vanadomolybdenum polyoxocation with a “metal-bonded” spherical framework. Inorg. Chem. 2002, 41, 4621−4623.
(12) Sheldrick, G. M. SADABS, Siemens Analytical X-ray Instrument Division. Madison, WI 1995.
(13) Sheldrick, G. M. Universität Görringen, Germany 1997.
(14) Soghomonian, V.; Chen, Q.; Haushalter, R. C.; Zubieta, J. Vanadium phosophate framework solid constructed of octahedral, square pyramids, and tetrahedra with a cavity dimension of 18.4 Å. Angew. Chem. Int. Ed. Engl. 1993, 32, 610–612.
(15) Khan, M. I.; Meyer, L. M.; Haushalter, R. C.; Schweitzer, A. L.; Zubieta, J. Dye, J. L. Giant voids in the hydrothermally synthesized microporous square pyramidal tetrahedral framework vanadium phosphates [HN(CH2CH2)3NH]K[V5O9(PO4)2]·xH2O and Cs3[V5O9(PO4)2]·xH2O. Chem. Mater. 1996, 8, 43–53.
(16) Zhang, Y.; Haushalter, R. C.; Clearfield, A. A heteropolyanion containing two linked mixed Mo/V pentadecaoxometalate clusters: structure of [Mo16V14O84]14-. J. Chem. Soc. Chem. Commun. 1995, 1149–1150.
(17) Müller, A.; Koop, M.; Schiffels, P.; Bogge, H. [{MoVI8VIV4O36(VVO4) (VIVO)2}n]7n-: capped α-Keggin fragments linked to a chain. Chem. Commun. 1997, 1715–1716.
(18) Brese, N. E.; O’Keeffe, M. Bond-valence parameters for solids. Acta. Crystallogr. 1991, B47, 192–197.
(20) Xu, Y.; Zhu, D.; Guo, Z.; Shi, Y.; Zhang, K.; You, X. Cation-induced assembly of the first mixed molybdenum-vanadium hexadecametal host shell cluster anions. J. Chem. Soc., Dalton. Trans. 2001, 772–773. |