Construction of <em>2D</em> Cd(II) Network with Homohelical Chains Based on 1,3-Dipyridyl benzene (Dpb) and 4,4'-Sulfonyldibenzoic Acid (H<sub>2</sub>sdb)

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摘要 A two-dimensional (2D) coordination polymer {[Cd₂(sdb)₂(dpb)₂]·3H₂O}_n (1) was prepared by solvothermal reaction of two types of V-shaped ligands: 1,3-dipyridyl benzene (dpb) and deprotonated 4,4΄-sulfonyldibenzoic acid(H₂sdb). It was characterized by elemental analysis, IR spectroscopy, and X-ray single-crystal diffraction. Complex 1 crystallizes in the monoclinic system, space group Fdd2 with a = 46.247(10), b = 9.994(2), c = 24.267(6) Å, V = 11216(4) Å³, C₆₀H₄₆Cd₂N₄O₁₅S₂, M_r = 1387.97, D_c = 1.559 g/cm³, F(000) = 5296.0, μ =0.902 mm^{-1 and Z = 8. Each [Cd(COO)]₂ cluster links four sdb^2- anions to form infinitely ABAB stacked 2D wave-like sheets, in which each sheet contains the same helical chains, and the helical directions of sheets A and B are reversed. Dpb links the rest coordinated sites of [(COO)Cd]₂ cluster to form a 2D network. In addition, the solid fluorescence of 1 and dpb is also studied.}

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	潘成岭
	张雷
	胡劲松

关键词 ： coordination polymer, V-shaped ligand, crystal structure, solid fluorescence

Abstract：A two-dimensional (2D) coordination polymer {[Cd₂(sdb)₂(dpb)₂]·3H₂O}_n (1) was prepared by solvothermal reaction of two types of V-shaped ligands: 1,3-dipyridyl benzene (dpb) and deprotonated 4,4΄-sulfonyldibenzoic acid(H₂sdb). It was characterized by elemental analysis, IR spectroscopy, and X-ray single-crystal diffraction. Complex 1 crystallizes in the monoclinic system, space group Fdd2 with a = 46.247(10), b = 9.994(2), c = 24.267(6) Å, V = 11216(4) Å³, C₆₀H₄₆Cd₂N₄O₁₅S₂, M_r = 1387.97, D_c = 1.559 g/cm³, F(000) = 5296.0, μ =0.902 mm^-1 and Z = 8. Each [Cd(COO)]₂ cluster links four sdb^2- anions to form infinitely ABAB stacked 2D wave-like sheets, in which each sheet contains the same helical chains, and the helical directions of sheets A and B are reversed. Dpb links the rest coordinated sites of [(COO)Cd]₂ cluster to form a 2D network. In addition, the solid fluorescence of 1 and dpb is also studied.

Key words： coordination polymer V-shaped ligand crystal structure solid fluorescence

收稿日期: 2014-03-24 出版日期: 2014-08-20

基金资助:This work was supported by the National Natural Science Foundation of China (21301005) and Natural Science Foundation of Anhui Province (1308085QB34, 1408085QB31)

通讯作者: 胡劲松 E-mail: hujinsong1982@126.com

引用本文:

潘成岭;张雷;胡劲松. Construction of 2D Cd(II) Network with Homohelical Chains Based on 1,3-Dipyridyl benzene (Dpb) and 4,4'-Sulfonyldibenzoic Acid (H₂sdb)[J]. 结构化学, 2014, 33(10): 1533-1538.
PAN Cheng-Ling;ZHANG Lei;HU Jin-Song. Construction of 2D Cd(II) Network with Homohelical Chains Based on 1,3-Dipyridyl benzene (Dpb) and 4,4'-Sulfonyldibenzoic Acid (H₂sdb). CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2014, 33(10): 1533-1538.

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http://manu30.magtech.com.cn/jghx/CN/ 或 http://manu30.magtech.com.cn/jghx/CN/Y2014/V33/I10/1533

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