Synthesis, Crystal Structure and Properties of a Copper Complex with the Bicycle[2.2.1]-2-heptene-5,6-dicarboxylic Acid

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摘要 A new copper complex 2{Cu(C₁₀H₈N₂)[C₈H₁₁O₂(COO)](H₂O)₃}·(H₂O)₅ with bicycle[2.2.1]hept-2-en-5,6-dicarboxylic acid (H2L) [C₇H₈(COOH)₂], basic copper carbonate and 2,2'-bipyridine has been synthesized in the mixed solvents of methanol and water. It crystallizes in the triclinic system, space group Pī,with α = 7.4626(5), b = 11.9779(8), c = 12.9841(8) Å, α = 109.7040(10), β = 98.7550(10), γ = 90.6240(10)º, V = 1077.50(12) Å³, D_c = 1.538 g/cm³, Z = 1, F(000) = 520, GOOF = 1.065, R= 0.0360 and wR= 0.0950. The copper ion is coordinated with four oxygen atoms from one H2L molecule and three water molecules together with two nitrogen atoms from the 2,2'-bipyridine molecule, forming a distorted octahedral coordination geometry. The thermal stabilityand electrochemical properties were also studied.

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	李薇
	李昶红
	李衡峰
	谭雄文

关键词 ： copper(II) complex, crystal structure, properties analysis

Abstract：A new copper complex 2{Cu(C₁₀H₈N₂)[C₈H₁₁O₂(COO)](H₂O)₃}·(H₂O)₅ with bicycle[2.2.1]hept-2-en-5,6-dicarboxylic acid (H2L) [C₇H₈(COOH)₂], basic copper carbonate and 2,2'-bipyridine has been synthesized in the mixed solvents of methanol and water. It crystallizes in the triclinic system, space group Pī,with α = 7.4626(5), b = 11.9779(8), c = 12.9841(8) Å, α = 109.7040(10), β = 98.7550(10), γ = 90.6240(10)º, V = 1077.50(12) Å³, D_c = 1.538 g/cm³, Z = 1, F(000) = 520, GOOF = 1.065, R= 0.0360 and wR= 0.0950. The copper ion is coordinated with four oxygen atoms from one H2L molecule and three water molecules together with two nitrogen atoms from the 2,2'-bipyridine molecule, forming a distorted octahedral coordination geometry. The thermal stabilityand electrochemical properties were also studied.

Key words： copper(II) complex crystal structure properties analysis

收稿日期: 2013-12-20 出版日期: 2014-07-17

基金资助:

Supported by the Natural Science Foundation of Hunan Province (No.11JJ9006), Key Project of Science and Technology Plan of Hunan Province (2012FJ2002) and the Construct Program of the Key Discipline in Hunan Province

通讯作者: Corresponding author. E-mail: lihengfeng@gmail.com E-mail: li_weihnxy@126.com

引用本文:

李薇;李昶红;李衡峰;谭雄文. Synthesis, Crystal Structure and Properties of a Copper Complex with the Bicycle[2.2.1]-2-heptene-5,6-dicarboxylic Acid[J]. 结构化学, 2014, 33(10): 1527-1532.
LI Wei;LI Chang-Hong;LI Heng-Feng;TAN Xiong-Wen. Synthesis, Crystal Structure and Properties of a Copper Complex with the Bicycle[2.2.1]-2-heptene-5,6-dicarboxylic Acid. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2014, 33(10): 1527-1532.

链接本文:

http://manu30.magtech.com.cn/jghx/CN/ 或 http://manu30.magtech.com.cn/jghx/CN/Y2014/V33/I10/1527

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