Crystal structure and Luminescent Properties of a Zn(II) Coordination Polymer Assembled by Mixed-ligand

摘要
图/表
参考文献(32)
相关文章 (15)

全文: PDF (793 KB) HTML (1 KB)
输出: BibTeX | EndNote (RIS)

摘要 A Zn(II) coordination polymer [Zn(NIP)(3,3'-bpt)]·H₂O (1, NIP = 5-nitroisophtha- late, 3,3'-bpt = 1H-3,5-bis(3-pyridyl)-1,2,4-triazolate) has been synthesized by the hydrothermal reaction at 140 ℃ and structurally characterized by IR spectroscopy, X-ray diffraction, thermal analysis, single-crystal X-ray diffraction and luminescent properties. In complex 1, the zinc atom is five-coordinated with three carboxylate oxygen atoms from three H₂NIP and two nitrogen atoms from two 3,3'-bpt, respectively, forming a distorted trigonal bipyramidal geometry and showing a 1D chain structure, which is further bridged by NIP to form a 3D supramolecular network via self-assembly of hydrogen bonds.

	服务

	把本文推荐给朋友
	加入我的书架
	加入引用管理器
	E-mail Alert
	RSS
	作者相关文章
	秦小焕
	邹华红
	桂柳成
	廖永志
	李海叶
	黄富平

关键词 ： Zn(II) coordination polymer, crystal structure, luminescent properties

Abstract：A Zn(II) coordination polymer [Zn(NIP)(3,3'-bpt)]·H₂O (1, NIP = 5-nitroisophtha- late, 3,3'-bpt = 1H-3,5-bis(3-pyridyl)-1,2,4-triazolate) has been synthesized by the hydrothermal reaction at 140 ℃ and structurally characterized by IR spectroscopy, X-ray diffraction, thermal analysis, single-crystal X-ray diffraction and luminescent properties. In complex 1, the zinc atom is five-coordinated with three carboxylate oxygen atoms from three H₂NIP and two nitrogen atoms from two 3,3'-bpt, respectively, forming a distorted trigonal bipyramidal geometry and showing a 1D chain structure, which is further bridged by NIP to form a 3D supramolecular network via self-assembly of hydrogen bonds.

Key words： Zn(II) coordination polymer crystal structure luminescent properties

收稿日期: 2014-01-08 出版日期: 2014-07-11

基金资助: Supported by the National Natural Science Foundattion of China (21101035), Natural Science Foundattion of Guangxi province (2012GXNSFBA053017), the Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources, Ministry of Education of China (CMEMR2013-A05) and the Natural Science Foundation of Guangxi Normal University

通讯作者: 秦小焕: E-mail: qinchengshi091129@163.com

引用本文:

秦小焕;邹华红;桂柳成;廖永志;李海叶;黄富平. Crystal structure and Luminescent Properties of a Zn(II) Coordination Polymer Assembled by Mixed-ligand[J]. 结构化学, 2014, 33(9): 1293-1299.
QIN Xiao-Huan;ZOU Hua-Hong;GUI Liu-Cheng;LIAO Yong-Zhi;LI Hai-Ye;HUANG Fu-Ping. Crystal structure and Luminescent Properties of a Zn(II) Coordination Polymer Assembled by Mixed-ligand. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2014, 33(9): 1293-1299.

链接本文:

http://manu30.magtech.com.cn/jghx/CN/ 或 http://manu30.magtech.com.cn/jghx/CN/Y2014/V33/I9/1293

(1) Eddaoudi, M.; Moler, D. B.; Li, H.; Chen, B.; Reineke, T. M.; O’Keeffe, M.; Yaghi, O. M. Modular chemistry: secondary building units as a basis for the design of highly porous and robust metal-organic carboxylate frameworks. Acc. Chem. Res. 2001, 34, 319-330.

(2) Zhang, J.; Chen, S.; Nieto, R. A.; Wu, T.; Feng, P.; Bu, X. A tale of three carboxylate: cooperative asymmetric crystallization of 3D microporous framework from achiral precurous. Angew. Chem. Int. Ed. 2010, 49, 1267-1270.

(3) Seo, J. S.; Whang, D.; Lee, H.; Jun, S. I.; Oh, J.; Jeon, Y. J.; Kim, K. A homochiral metal-organic porous material for enantioselective separation and catalysis. Nature 2000, 404 , 982-986.

(4) Evans, O. R.; Xiong, R. G.; Wang, Z. Y.; Wong, G. K.; Lin, W. B. Crystal engineering of acentric diamondoid metal-organic coordination networks. Angew. Chem. Int. Ed. 1999, 38, 536-538.

(5) Lin, W.; Evans, O. R.; Xiong, R. G.; Wang, Z. Synthesis, structures, and second-order nonlinear optical properties of bis(nicotinato) zinc and bis{3-[2-(4-pyridyl)ethenyl]benzoato} cadmium. J. Am. Chem. Soc. 1998, 120, 13272-13273.

(6) Huang, F. P.; Tian, J. L.; Chen, G. J.; Li, D. D.; Gu, W.; Liu, X.; Yan, S. P.; Liao, D. Z.; Cheng, P. A case study of the Zn^II-BDC/bpt mixed-ligand system: positional isomeric effect, structural diversification and luminescent properties. CrystEngComm. 2010, 12, 1269-1279.

(7) Zhang, J. P.; Zhang, Y. B.; Lin, J. B.; Chen, X. M. Metal azolate frameworks: from crystal engineering to functional materials. Chem. Rev. 2012, 112, 1001-1033.

(8) Kleij, A. W.; Kuil, M.; Tooke, D. M.; Lutz, M.; Spek, A. L.; Reek, J. N. H. Zn^II-salphen complexes as versatile building blocks for the construction of supramolecular box assemblies. Chem. Eur. J. 2005, 11, 4743-4750.

(9) Ma, D. Y.; Guo, H. F.; Lu, K.; Pan, Y.; Qin, L.; Blatov, V. A. A 1D → 3D two-fold interpenetration array formed by hydrogen-bonding interactions. Z. Anorg. Allg. Chem. 2012, 638, 992-995.

(10) Eddaoudi, M.; Li, H.; Yaghi, O. M. Highly porous and stable metal-organic frameworks: structure design and sorption properties. J. Am. Chem. Soc. 2000, 122, 1391-1397.

(11) Zhang, M. B.; Zhang, J.; Zheng, S. T.; Yang, G. Y. A 3D coordination framework based on linkages of nanosized hydroxo lanthanide clusters and copper centers by isonicotinate ligands. Angew. Chem. Int. Ed. 2005, 44, 1385-1388.

(12) Wang, X. L.; Xia, Z. Q.; Wei, W.; Xie, G.; Chen S. P.; Gao, S. L. Synthesis, structure, and thermodynamics of a lanthanide coordination compound incorporating 5-nitroisophthalic acid. J. Chem. Therm. 2012, 55, 124-129.

(13) Gu, X. J.; Xue, D. F. Selected controlled synthesis of three dimensional 4d-4f heterometallic coordination frameworks by lanthanide carboxylate subunits and silver centers. Cryst. Growth. Design 2006, 6, 2551-2557.

(14) Wang, X. Y.; Li, X. M.; Niu, Y. L.; Wang, Q. W.; Liu, B.; Wang, Z. T. Hydrothermal synthesis, crystal structure and photoluminescent property of a zinc(II) complex with 2,2΄-diphenic acid and 2,2΄-bipyridine ligands. Chin. J. Struct. Chem. 2010, 11, 1680-1683.

(15) Murugavel, R.; Krishnamurthy D.; Sathiyendiran, M. Anionic metal-organic and cationic layer alternation in the coordination polymers [{M(BTEC)(OH₂)₄}·{C4H₁₂N₂}·4H₂₀]_n (M = Co, Ni, and Zn; BTEC = 1,2,4,5-benzenetetracarboxylate). J. Chem. Soc. Dalton Trans. 2002, 1, 34-39.

(16) Tao, J.; Yin, X.; Wei, Z. B.; Huang, R. B.; Zheng, L. S. Hydrothermal syntheses, crystal structures and photoluminescent properties of three metal-cluster based coordination polymers containing mixed organic ligands. Eur. J. Inorg. Chem. 2004, 2004, 125-133.

(17) Luo, J. H.; Hong, M. C.; Cao, R.; Liang, Y. C.; Zhao, Y. J.; Wang, R. H.; Weng, J. B. Syntheses and crystal structure of cadmium(II) coordination polymers with end-to-end dicyanamide bridges. Polyhedron 2002, 21, 893-898.

(18) Zhang, H. T.; Song, Y.; Li, Y. X.; Zuo, J. L.; Gao, S.; You, X. Z. Three-dimensional lanthanoid-containing coordination frameworks: structure, magnetic and fluorescent properties. Eur. J. Inorg. Chem. 2005, 2005, 766-772.

(19) Ye, B. H.; Tong, M. L.; Chen, X. M. Metal-organic molecular architectures with 2,2΄-bipyridyl-like and carboxylate ligands. Coord. Chem. Rev. 2005, 249, 545-565.

(20) Du, M.; Jiang, X. J.; Zhao, X. J. Direction of unusal mixed-ligand metal-organic frameworks: a new type of 3D polythreading involving 1D and 2D structural motifs and a 2-fold interpenetrating porous network. Chem. Commun. 2005, 44, 5521-5523.

(21) Herbst, R. M.; Garrison, J. A. Studies on the formation of 4-aminotriazole derivatives from acyl hydraxides. J. Org. Chem. 1953, 18, 872-877.

(22) Bruker. APEXII software, Version 6.3.1, Bruker AXS Inc, Madison, Wisconsin, USA 2004.

(23) Sheldrick, G. M. SHELXS-97 and SHELXL-97, Program for X-ray Crystal Structure Refinement. Univrsity of Göttingen, Germany1997.

(24) Huang, F. P.;Tian, J. L.; Gu, W.; Yan, S. P. Three 3D Cu(II) coordination polymers constructed from 1,2,4,5-benzenetetracarboxylate acid and three positional isomeric ligands.Inorg. Chem. Comm. 2010, 13, 90-94.

(25) Huang, F. P.; Zhang, Q.; Yu, Q.; Bian, H. D.; Liang, H.; Yan, S. P.; Liao, D. Z.; Cheng, P. Coordination assemblies of Co^II/Ni^II/Zn^II/Cd^II with succinic acid and bent connectors: structural diversity and spin-canted antiferromagnetism. Cryst. Growth. Design 2012, 12, 1890-1898.

(26) Xiang, J.; Wu, J. S. Synthesis, structure, electrochemistry, and spectroscopy of two ruthenium(II) complexes containing [1,2,3] triazolo [1,5a] pyridine. Z. Anorg. Allg. Chem. 2013, 639, 606-610.

(27) Chen, C. J.; Ye, X. P.; Gao, J. J.; Xie, W. P.; Ran, X. R.; Yue, S. T.; Cai, Y. P. Auxiliary ligand-directed synthesis of four novel functional supramolecular metal-organic frameworks from 1-D chains to 3-D architectures. Inorg. Chem. Comm. 2013, 29, 4-10.

(28) Wu, B.; Yuan, D.; Jiang, F.; Wang, R.; Han, L.; Zhou, Y.; Hong, M. Metal-directed self-assembly: two new metal-binicotinate grid polymeric networks and their fluorescence emmission tuned by ligand configuration. Eur. J. Inorg. Chem. 2004, 13, 2695-2700.

(29) Jiao, C. M.; Zhang, W. H.; Tang, X. Y.; Liu, L. L.; Zhang, Y.; Lang, J. P. Fornation of a 1D water chain into the channel of a unique 3D hydrogen-bound coordination polymer {[Cd(μ-Cl)(4-pya)(H₂O)]₂·4H₂O}_∞ (4-pya = trans-4-pyridylacrylate). Inorg. Chem. Comm. 2007, 10, 975-978.

(30) Pliss, A.; Zhao, L. L.; Ohulchanskyy, T. Y.; Qu, J. L.; Prasad, P. N. Fluorescence lifetime of fluorescent proteins as an intracellular environment probe sensing the cell cycle progression. ACS Chem. Biol. 2012, 7, 1385-1392.

(31) Chen, J. Y.; Selvin, P. R. Lifetime- and color-tailored fluorophores in the micro- to millisecond time regime. J. Am. Chem. Soc. 2000, 122, 657-660.

(32) McManus, G. J.; Perry IV, J. J.; Perry, M.; Wagner, B. D.; Zaworotko, M. J. Exciplex fluorescence as a diagnostic probe of structure in coordination polymers of Zn²⁺ and 4,4΄-bipyridine containing intercalated pyrene and enclathrated aromatic solvent guests. J. Am. Chem. Soc. 2007, 129, 9094-9101.