Synthesis and Characterization of a New 2D Ca (II) Coordination Polymer Containing 1D Calcium–oxygen Chains

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摘要 A new 2D Ca(II) coordination polymer, [Ca(H₂btc)(H₂O)₂]_n(1, H₄btc = biphenyl- 3,3΄,5,5΄-tetracarboxylic acid), has been synthesized using the hydrothermal method and cha- racterized by single-crystal X-ray diffraction, elemental analysis, IR,thermogravimetric analysis, and photoluminescentanalysis. Complex 1 crystallizes in the monoclinic system, space group C2/c with α = 17.5676(15), b = 11.4496(8), c = 7.6197(8) Å, β = 102.787(2)º, V = 1494.6(2) Å³, Z = 4, D_c = 1.797 Mg·m^-3, μ = 0.483 mm^-1, F(000) = 832, the final R = 0.0348 and wR = 0.0915 for 1521 observed reflections with I > 2σ(I). Complex 1 hasa2D network containing 1D calcium-oxygen chains. These 2D networks are further connected by O–H···O hydrogen bonding interactions to generate a 3D supramolecular structure.

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	王记江
	唐龙
	侯向阳
	高楼军
	付峰
	张美丽

关键词 ： coordination polymer, calcium-oxygen chains, photoluminescent property

Abstract：A new 2D Ca(II) coordination polymer, [Ca(H₂btc)(H₂O)₂]_n(1, H₄btc = biphenyl- 3,3΄,5,5΄-tetracarboxylic acid), has been synthesized using the hydrothermal method and cha- racterized by single-crystal X-ray diffraction, elemental analysis, IR,thermogravimetric analysis, and photoluminescentanalysis. Complex 1 crystallizes in the monoclinic system, space group C2/c with α = 17.5676(15), b = 11.4496(8), c = 7.6197(8) Å, β = 102.787(2)º, V = 1494.6(2) Å³, Z = 4, D_c = 1.797 Mg·m^-3, μ = 0.483 mm^-1, F(000) = 832, the final R = 0.0348 and wR = 0.0915 for 1521 observed reflections with I > 2σ(I). Complex 1 hasa2D network containing 1D calcium-oxygen chains. These 2D networks are further connected by O–H···O hydrogen bonding interactions to generate a 3D supramolecular structure.

Key words： coordination polymer calcium-oxygen chains photoluminescent property

收稿日期: 2014-02-09 出版日期: 2014-06-09

基金资助:This project was supported by the National Natural Science Foundation of China (No. 21373178) and the Natural Scientific Research Foundation of Shaanxi Provincial Education Office of China (No. 13JS124)

作者简介: 王记江: yadxwjj@126.com

引用本文:

王记江;唐龙;侯向阳;高楼军;付峰;张美丽. Synthesis and Characterization of a New 2D Ca (II) Coordination Polymer Containing 1D Calcium–oxygen Chains[J]. 结构化学, 2014, 33(7): 1069-1073.
WANG Ji-Jiang;TANG Long;HOU Xiang-Yang;GAO Lou-Jun;FU Feng;ZHANG Mei-Li. Synthesis and Characterization of a New 2D Ca (II) Coordination Polymer Containing 1D Calcium–oxygen Chains. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2014, 33(7): 1069-1073.

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http://manu30.magtech.com.cn/jghx/CN/ 或 http://manu30.magtech.com.cn/jghx/CN/Y2014/V33/I7/1069

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