Graphene Oxide/Fe<sub>3</sub>O<sub>4</sub> Magnetic Nanocomposites for Efficient Recovery of Indium

doi:10.14102/j.cnki.0254–5861.2011–3161

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摘要 Adsorbent has been widely used for the recovery and enrichment of rare metals from waste water. Herein, a graphene-based adsorbent, graphene oxide/Fe3O4 (GO/Fe3O4) nanocomposite, was prepared by a facile hydrothermal method, and characterized by X-ray diffraction, Scanning Electron Microscope, X-ray Photoelectron Spectroscopy, Zeta potential and magnetization. The material has been explored for the recovery of In from simulated waste water. The test results show that the nanocomposite has a reasonable adsorption capacity on indium in a wide pH range, e.g., the adsorption percent and quantity of In(Ⅲ) from the aqueous solutions at pH = 4 and C0 = 50 mg·L−1 are 91% and 43.98 mg·L−1, respectively. In addition, the nanocomposites maintain a 75.5% cycling capacity and a 71% removal efficiency after five continuous cycles due to their novel properties of high specific surface area and superparamagnetism. The pseudo-second-order adsorption model can be used to interpret the kinetic data. High adsorption efficiency and good reusability can make the nanocomposite a promising adsorbent for recovery of In(Ⅲ).

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	王令航
	邱智华
	池利生

关键词 ： adsorbent, graphene oxide, Fe₃O₄ magnetic nanoparticles (NPs), nanocomposites, In(Ⅲ)

Abstract：Adsorbent has been widely used for the recovery and enrichment of rare metals from waste water. Herein, a graphene-based adsorbent, graphene oxide/Fe3O4 (GO/Fe3O4) nanocomposite, was prepared by a facile hydrothermal method, and characterized by X-ray diffraction, Scanning Electron Microscope, X-ray Photoelectron Spectroscopy, Zeta potential and magnetization. The material has been explored for the recovery of In from simulated waste water. The test results show that the nanocomposite has a reasonable adsorption capacity on indium in a wide pH range, e.g., the adsorption percent and quantity of In(Ⅲ) from the aqueous solutions at pH = 4 and C0 = 50 mg·L−1 are 91% and 43.98 mg·L−1, respectively. In addition, the nanocomposites maintain a 75.5% cycling capacity and a 71% removal efficiency after five continuous cycles due to their novel properties of high specific surface area and superparamagnetism. The pseudo-second-order adsorption model can be used to interpret the kinetic data. High adsorption efficiency and good reusability can make the nanocomposite a promising adsorbent for recovery of In(Ⅲ).

Key words： adsorbent graphene oxide Fe₃O₄ magnetic nanoparticles (NPs) nanocomposites In(Ⅲ)

收稿日期: 2021-02-26 出版日期: 2021-11-04

基金资助:This work is supported by the FJIRSM&IUE Joint Research Fund (No. RHZX-2018-006)

通讯作者: lchi@fjirsm.ac.cn E-mail: lchi@fjirsm.ac.cn

引用本文:

王令航;邱智华;池利生. Graphene Oxide/Fe₃O₄ Magnetic Nanocomposites for Efficient Recovery of Indium[J]. 结构化学, 2021, 40(11): 1423-1432.
WANG Ling-Hang;QIU Zhi-Hua;CHI Li-Sheng. Graphene Oxide/Fe₃O₄ Magnetic Nanocomposites for Efficient Recovery of Indium. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2021, 40(11): 1423-1432.

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http://manu30.magtech.com.cn/jghx/CN/10.14102/j.cnki.0254–5861.2011–3161 或 http://manu30.magtech.com.cn/jghx/CN/Y2021/V40/I11/1423

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