A New Dinuclear Zinc Polymer Based on 3-Methoxy-2-hydroxybenzaldehyde:Synthesis, Structure, Spectral Characterization and Hirshfeld Surface Analysis
易茗;赵儒霞;王敦球;肖瑜
Guangxi Collaborative Innovation Center for Water Pollution Control and Water Safety in Karst Area, Guilin University of Technology, Guilin 541004, China
A New Dinuclear Zinc Polymer Based on 3-Methoxy-2-hydroxybenzaldehyde:Synthesis, Structure, Spectral Characterization and Hirshfeld Surface Analysis
YI Ming;ZHAO Ru-Xia;WANG Dun-Qiu;XIAO Yu
Guangxi Collaborative Innovation Center for Water Pollution Control and Water Safety in Karst Area, Guilin University of Technology, Guilin 541004, China
A highly efficient fluorescence material dinuclear zinc polymer [Zn2(mhbd)2(dca)2]n (1, Hmhbd is 3-methoxy-2-hydroxybenzaldehyde, dca is N(CN)2‒) has been synthesized under room temperature and structurally characterized by elemental analysis, IR, and single-crystal X-ray diffraction. The structure belongs to the triclinic system, space group P with a = 8.475(1), b = 9.595(1), c = 15.001(1) Å, α = 86.84(1), β = 81.10(1), γ = 68.78(1)°, Mr = 565.15, V = 1123.5(1) Å3, Dc = 1.671 g•cm–3, F(000) = 568, μ = 2.185 mm–1, R = 0.0451, and wR = 0.1297. 1 is a dinuclear zinc complex which further constructs a 1D chain through double μ1,5-dca bridge. Luminescent property and Hirshfeld surface analysis of 1 have been studied. The result indicates that the fluorescence intensity of complex 1 is forty-one times the fluorescence intensity of Hmhbd ligand.
A highly efficient fluorescence material dinuclear zinc polymer [Zn2(mhbd)2(dca)2]n (1, Hmhbd is 3-methoxy-2-hydroxybenzaldehyde, dca is N(CN)2‒) has been synthesized under room temperature and structurally characterized by elemental analysis, IR, and single-crystal X-ray diffraction. The structure belongs to the triclinic system, space group P with a = 8.475(1), b = 9.595(1), c = 15.001(1) Å, α = 86.84(1), β = 81.10(1), γ = 68.78(1)°, Mr = 565.15, V = 1123.5(1) Å3, Dc = 1.671 g•cm–3, F(000) = 568, μ = 2.185 mm–1, R = 0.0451, and wR = 0.1297. 1 is a dinuclear zinc complex which further constructs a 1D chain through double μ1,5-dca bridge. Luminescent property and Hirshfeld surface analysis of 1 have been studied. The result indicates that the fluorescence intensity of complex 1 is forty-one times the fluorescence intensity of Hmhbd ligand.
This work was financially supported by the National Natural Science Foundation of China (Nos. 51638006 and 51569008) and the Natural Science Foundation of Guangxi Province (No. 2015GXNSFAA139240)
易茗;赵儒霞;王敦球;肖瑜. A New Dinuclear Zinc Polymer Based on 3-Methoxy-2-hydroxybenzaldehyde:Synthesis, Structure, Spectral Characterization and Hirshfeld Surface Analysis[J]. 结构化学, 2018, 37(2): 312-321.
YI Ming;ZHAO Ru-Xia;WANG Dun-Qiu;XIAO Yu. A New Dinuclear Zinc Polymer Based on 3-Methoxy-2-hydroxybenzaldehyde:Synthesis, Structure, Spectral Characterization and Hirshfeld Surface Analysis. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2018, 37(2): 312-321.
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