a(Department of Chemistry, Zunyi Normal College, Zunyi, Guizhou 563002, China)
b (School of Chemical Science and Technology, Yunnan University, Kunming 650091, China)
Helical Coordination Polymer with a 3-Fold Interpenetration Structure Based on 5-(Hydroxymethyl)isophthalic Acid
XU Zhong-Xuan;MA Yu-Lu
a(Department of Chemistry, Zunyi Normal College, Zunyi, Guizhou 563002, China)
b (School of Chemical Science and Technology, Yunnan University, Kunming 650091, China)
5-羟甲基间苯二甲酸（H2HIA））作为一种新颖的有机配体，已由3,5-双甲氧羰基苯甲酸经两步反应制备出。在160℃的水热合成条件下，利用H2HIA与1, 2-二(4-吡啶基)乙烯(DPEE)配体和Zn2+ 离子组装出了一种具有三重穿插结构的螺旋配位聚合物，也就是[Zn1/2(HIA)1/2(DPEE)1/2]n (1)。化合物1结晶于正交体系，空间群是Pnna，具有 a = 8.2118(5), b = 17.1698(7), c =14.9922(7) Å, V = 2113.82(18) Å3, μ = 1.194 mm-1, Z = 4 和 S = 0.967的晶体参数。此外，对化合物1的一些物理特征，比如粉末X射线衍射、热失重分析和荧光性质也进行了调查。
5-(Hydroxymethyl) isophthalic acid (H2HIA) as a novel organic ligand was prepared from 3,5-bis(methoxycarbonyl)benzoic acid by a two-step method. And then, a 3D helical coor- dination polymer with a 3-fold interpenetration structure, namely [Zn1/2(HIA)1/2(DPEE)1/2]n (1), was hydrothermally synthesized at 160 ℃, using H2HIA ligands to assemble with DPEE ligands and Zn2+ ions. Complex 1 crystalizes in orthorhombic system, space group Pnna, with a = 8.2118(5), b = 17.1698(7), c =14.9922(7) Å, V = 2113.82(18) Å3, μ = 1.194 mm-1, Z = 4 and S = 0.967. Moreover, some physical characteristics of complex 1, such as powder X-ray diffraction (PXRD), thermogravimetry analyses (TGA) and photoluminescent properties, were also investigated.
This work was supported by the Natural Science Foundation of Guizhou Province (20122344), 125 program of Guizhou Education Department (2012015) and the Doctoral Scientific Fund of Zunyi Normal College (2012BSJJ12)
徐中轩;马钰璐. 一种基于5-羟甲基间苯二甲酸具有三重穿插结构的螺旋配位聚合物[J]. 结构化学, 2017, 36(7): 1193-1198.
XU Zhong-Xuan;MA Yu-Lu. Helical Coordination Polymer with a 3-Fold Interpenetration Structure Based on 5-(Hydroxymethyl)isophthalic Acid. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2017, 36(7): 1193-1198.
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2017, Vol. 36 
