A Novel 3D Twofold Zn(II) Coordination Polymer Constructed by Mixed Flexible Ligands: Synthesis,  Crystal Structure and Fluorescence Property

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摘要

A new Zn(Ⅱ) coordination polymer , {[Zn(1,3-bip)(oba)]?0.5H2O}n (1), where 1,3-bip is 1,3-bis(imidazole)propane, H2oba is 4,4’-oxybis(benzoate) , have been synthesized and characterized by single crystal X-ray diffraction, powder XRD, FTIR, TGA and elemental analysis techniques. The single crystal X-ray diffraction reveals that complex 1 shows a 3D→3D twofold interpenetrating network that can be described as a 4-connected uninodal net with (6^5.8) topology. In addition, the photoluminescence property of complex 1 was also investigated at room temperature.

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	李培煊
	卢久富

关键词 ： Zn(II) coordination polymer, twofold interpenetrating, photoluminescence property

Abstract：A new Zn(Ⅱ) coordination polymer , {[Zn(1,3-bip)(oba)]?0.5H2O}n (1), where 1,3-bip is 1,3-bis(imidazole)propane, H2oba is 4,4’-oxybis(benzoate) , have been synthesized and characterized by single crystal X-ray diffraction, powder XRD, FTIR, TGA and elemental analysis techniques. The single crystal X-ray diffraction reveals that complex 1 shows a 3D→3D twofold interpenetrating network that can be described as a 4-connected uninodal net with (6^5.8) topology. In addition, the photoluminescence property of complex 1 was also investigated at room temperature.

Key words： Zn(II) coordination polymer twofold interpenetrating photoluminescence property

收稿日期: 2015-11-19 出版日期: 2017-02-13

基金资助:Supported by the National Youth Natural Science Foundation of China (No. 21603133)

通讯作者: jiufulu@163.com E-mail: jiufulu@163.com

引用本文:

李培煊;卢久富. A Novel 3D Twofold Zn(II) Coordination Polymer Constructed by Mixed Flexible Ligands: Synthesis, Crystal Structure and Fluorescence Property[J]. 结构化学, 2017, 36(2): 303-309.
LI Pei-Xuan;LU Jiu-Fu. A Novel 3D Twofold Zn(II) Coordination Polymer Constructed by Mixed Flexible Ligands: Synthesis, Crystal Structure and Fluorescence Property. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2017, 36(2): 303-309.

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http://manu30.magtech.com.cn/jghx/CN/ 或 http://manu30.magtech.com.cn/jghx/CN/Y2017/V36/I2/303

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