Solvothermal Synthesis and Characterization of [TM(1,2-dap)3]HgSb2Se5 (TM = Co, Fe) with a Chain Structure
赵丽佳;赵日格吐;韩文静;白音孟和
a (College of Chemistry & Environmental Science,Innner Mongolia Normal University, Hohhot 010022, China)
b (Key Laboratory for Physics and Chemistry of Functional Materials, Inner Mongolia, Hohhot 010022, China)
Solvothermal Synthesis and Characterization of [TM(1,2-dap)3]HgSb2Se5 (TM = Co, Fe) with a Chain Structure
a (College of Chemistry & Environmental Science,Innner Mongolia Normal University, Hohhot 010022, China)
b (Key Laboratory for Physics and Chemistry of Functional Materials, Inner Mongolia, Hohhot 010022, China)
One organic-decorated quanternaery [TM(1,2-dap)3]HgSb2Se5(1,2-dap = 1,2-dia- ninopropane, TM = Co (1), Fe (2)) compound has been solvothermally synthesized. The compounds crystallize in triclinic space group P , with a = 11.248(6), b = 11.542(7), c = 12.180(12) Å, V = 1268.7(16) Å3, Z = 2, F(000) = 1010 for 1 and a = 11.311(5), b = 11.558(5), c = 12.180(9) Å, V = 1276.5(12) Å3, Z = 2, F(000) = 1008 for 2. The crystal structure consists of one-dimensional anionics chains composed of HgSe4 tetrahedra and SbSe3 trigonal pyramids sharing corners and [TM(dap)3]2+ cations. The [HgSb2Se52-]∞ anionic chains run along the [001] direction, and are surrounded by the [TM(dap)3]2+ cations. Meanwhile, 8-ring [Hg2Sb2Se4] and 6-ring [HgSb2Se2] are alternately found. The compounds were structurally characterized by elemental analysis, thermogravimetric analysis, infrared spectroscopy and UV-Vis diffuse reflectance spectroscopy.
One organic-decorated quanternaery [TM(1,2-dap)3]HgSb2Se5(1,2-dap = 1,2-dia- ninopropane, TM = Co (1), Fe (2)) compound has been solvothermally synthesized. The compounds crystallize in triclinic space group P , with a = 11.248(6), b = 11.542(7), c = 12.180(12) Å, V = 1268.7(16) Å3, Z = 2, F(000) = 1010 for 1 and a = 11.311(5), b = 11.558(5), c = 12.180(9) Å, V = 1276.5(12) Å3, Z = 2, F(000) = 1008 for 2. The crystal structure consists of one-dimensional anionics chains composed of HgSe4 tetrahedra and SbSe3 trigonal pyramids sharing corners and [TM(dap)3]2+ cations. The [HgSb2Se52-]∞ anionic chains run along the [001] direction, and are surrounded by the [TM(dap)3]2+ cations. Meanwhile, 8-ring [Hg2Sb2Se4] and 6-ring [HgSb2Se2] are alternately found. The compounds were structurally characterized by elemental analysis, thermogravimetric analysis, infrared spectroscopy and UV-Vis diffuse reflectance spectroscopy.
基金资助:This project was supported by the National Natural Science Foundation of China (No. 21461019)
通讯作者:
baiymh@163.com
E-mail: baiymh@163.com
引用本文:
赵丽佳;赵日格吐;韩文静;白音孟和. Solvothermal Synthesis and Characterization of [TM(1,2-dap)3]HgSb2Se5 (TM = Co, Fe) with a Chain Structure[J]. 结构化学, 2016, 35(8): 1222-1230.
ZHAO Li-Jia;ZHAORI Getu;HAN Wen-Jing;BAIYIN Menghe. Solvothermal Synthesis and Characterization of [TM(1,2-dap)3]HgSb2Se5 (TM = Co, Fe) with a Chain Structure. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2016, 35(8): 1222-1230.
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