Syntheses and Structural Characterization of Multi-component Chalcogenide Compounds Based on Pyridine/1,2-Ethanedithiol Solvent

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摘要 Reactions of Sn powder, cadmium iodide, rubidium carbonate, and sodium sulfide yielded two new compounds: three-dimensional chalcogenide RbNa3Cd2Sn2S8 (1) and layered ternary compound Na2CdS2 (2). 1 and 2 have been determined by single-crystal X-ray diffraction: 1 belongs to the orthorhombic space group Pca21, with a = 13.486(3), b = 6.7310(14), c = 18.401(4) Å and Z = 4; 2 crystallizes in the R m space group, with a = 3.718(3), c = 26.170(4) Å and Z = 3. Study of the yellow block shaped crystals of 1 reveals that the structure consists of tetrahedral CdS4 and SnS4. The {Cd2Sn2S8} cluster shows a 12-numbered ring structure assembled by corner-sharing of alternating SnS4 and CdS4, and the rubidium and sodium ions act as void-filling and charge compensating cations. The dark orange hexagonal crystal of compound 2 consists of a unique [CdS2]2- layer, which are separated by the Na+. UV/Vis absorption spectrum exhibits the materials 1 and 2 have semiconductor properties.

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	刘芳
	乌兰格日乐
	达力玛
	包永胜
	白音孟和

关键词 ： solvothermal synthesis, tin, cadmium, crystal structure

Abstract：Reactions of Sn powder, cadmium iodide, rubidium carbonate, and sodium sulfide yielded two new compounds: three-dimensional chalcogenide RbNa3Cd2Sn2S8 (1) and layered ternary compound Na2CdS2 (2). 1 and 2 have been determined by single-crystal X-ray diffraction: 1 belongs to the orthorhombic space group Pca21, with a = 13.486(3), b = 6.7310(14), c = 18.401(4) Å and Z = 4; 2 crystallizes in the R m space group, with a = 3.718(3), c = 26.170(4) Å and Z = 3. Study of the yellow block shaped crystals of 1 reveals that the structure consists of tetrahedral CdS4 and SnS4. The {Cd2Sn2S8} cluster shows a 12-numbered ring structure assembled by corner-sharing of alternating SnS4 and CdS4, and the rubidium and sodium ions act as void-filling and charge compensating cations. The dark orange hexagonal crystal of compound 2 consists of a unique [CdS2]2- layer, which are separated by the Na+. UV/Vis absorption spectrum exhibits the materials 1 and 2 have semiconductor properties.

Key words： solvothermal synthesis tin cadmium crystal structure

收稿日期: 2015-08-28 出版日期: 2016-06-03

基金资助:

This project was supported by the National Natural Science Foundation of China (No.21461019)

通讯作者: baiymh@163.com E-mail: baiymh@163.com

引用本文:

刘芳;乌兰格日乐;达力玛;包永胜;白音孟和. Syntheses and Structural Characterization of Multi-component Chalcogenide Compounds Based on Pyridine/1,2-Ethanedithiol Solvent[J]. 结构化学, 2016, 35(6): 946-952.
LIU Fang;WULAN Gerile;DA Lima;BAO Yong-Sheng;BAIYIN Meng He. Syntheses and Structural Characterization of Multi-component Chalcogenide Compounds Based on Pyridine/1,2-Ethanedithiol Solvent. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2016, 35(6): 946-952.

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http://manu30.magtech.com.cn/jghx/CN/ 或 http://manu30.magtech.com.cn/jghx/CN/Y2016/V35/I6/946

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