Syntheses, Structures, and Properties of Three New Polymers Based on Flexible and Rigid Ligands

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摘要

Three new supramolecular polymers, [(IP)(H2SO4)(H2O)] (1), [(H2SDC)(BPA)] (2) and [Mn(SDC)(IP)2]n (3), have been constructed by three modes (rigid IP, rigid SDC + flexible BPA, rigid IP + rigid SDC). Polymers 1 and 2 are supramolecular structures, assembled by hydrogen bonds and π•••π interactions. X-ray structure analysis of 3 shows waved 1D chains which form a 3D supramolecular network by hydrogen bonds and π•••π interactions. Solid-state properties of thermal stability, luminescent properties, and X-ray powder diffractions for these crystalline materials have also been investigated, and polymer 3 is considered to be a good stable luminescence material.

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	黄文欢
	刘潼
	王艳鑫
	刘淑雅
	李嘉智
	殷海菊
	张亚男

关键词 ： rigid ligand, flexible ligand, coordination polymers, supramolecular polymer, luminescence

Abstract：Three new supramolecular polymers, [(IP)(H2SO4)(H2O)] (1), [(H2SDC)(BPA)] (2) and [Mn(SDC)(IP)2]n (3), have been constructed by three modes (rigid IP, rigid SDC + flexible BPA, rigid IP + rigid SDC). Polymers 1 and 2 are supramolecular structures, assembled by hydrogen bonds and π•••π interactions. X-ray structure analysis of 3 shows waved 1D chains which form a 3D supramolecular network by hydrogen bonds and π•••π interactions. Solid-state properties of thermal stability, luminescent properties, and X-ray powder diffractions for these crystalline materials have also been investigated, and polymer 3 is considered to be a good stable luminescence material.

Key words： rigid ligand flexible ligand coordination polymers supramolecular polymer luminescence

收稿日期: 2015-07-16 出版日期: 2016-04-11

基金资助:

This work was supported by the National Natural Science Foundation of China (No. 21401121), Natural Science Foundation
of Shaanxi Province (No. 2014JQ2061) and Doctor Foundation of Shaanxi Unversity of Science & Technology (BJ14-22)

通讯作者: huangwenhuan@sust.edu.cn E-mail: huangwenhuan@sust.edu.cn

引用本文:

黄文欢;刘潼;王艳鑫;刘淑雅;李嘉智;殷海菊;张亚男. Syntheses, Structures, and Properties of Three New Polymers Based on Flexible and Rigid Ligands[J]. 结构化学, 2016, 35(4): 621-632.
HUANG Wen-Huan;LIU Tong;WANG Yan-Xin;LIU Shu-Ya;LI Jia-Zhi;YIN Hai-Ju;ZHANG Ya-Nan. Syntheses, Structures, and Properties of Three New Polymers Based on Flexible and Rigid Ligands. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2016, 35(4): 621-632.

链接本文:

http://manu30.magtech.com.cn/jghx/CN/ 或 http://manu30.magtech.com.cn/jghx/CN/Y2016/V35/I4/621

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