The title complex bis(2-acetylpyridine thiosemicarbazonato)-indium(iii) perchlo- rate hydrate has been synthesized by the reaction of 2-acetylpyridine thiosemicarbazide (L) with indium(iii) perchlorate, and its structure was characterized by elemental analysis, IR and single-crystal X-ray diffraction. The crystal of the title compound ([In(C8H9N4S)2]ClO4.H2O) belongs to monoclinic, space group P21/c with a = 12.6438(18), b = 12.6259(18), c = 15.116(2) nm, β = 105.800(2)°, Z = 4, V = 2321.9(6) nm3, Mr = 618.79, Dc = 1.770 g/cm3, μ = 1.359 mm-1, F(000) = 1240, R = 0.0265 and wR = 0.0675. X-ray analysis indicates that various intriguing hydrogen patterns involving both the solvent intermedia and polyatomic counterions play crucial roles in the self-assembly of functional supramolecules.
The title complex bis(2-acetylpyridine thiosemicarbazonato)-indium(iii) perchlo- rate hydrate has been synthesized by the reaction of 2-acetylpyridine thiosemicarbazide (L) with indium(iii) perchlorate, and its structure was characterized by elemental analysis, IR and single-crystal X-ray diffraction. The crystal of the title compound ([In(C8H9N4S)2]ClO4.H2O) belongs to monoclinic, space group P21/c with a = 12.6438(18), b = 12.6259(18), c = 15.116(2) nm, β = 105.800(2)°, Z = 4, V = 2321.9(6) nm3, Mr = 618.79, Dc = 1.770 g/cm3, μ = 1.359 mm-1, F(000) = 1240, R = 0.0265 and wR = 0.0675. X-ray analysis indicates that various intriguing hydrogen patterns involving both the solvent intermedia and polyatomic counterions play crucial roles in the self-assembly of functional supramolecules.
2011, Vol. 30 
