摘要One dinuclear manganese(II) complex[Mn2(C12H8N2)4(C8H5O4)2](C8H4O4)·H2O has been synthesized with o- phthalic acid and 1,10–phenanthroline . The crystal structure was determined by X-ray diffraction. The crystal belongs to the triclinic system,space group P-1 with a =1.17767(3) , b =1.22292(2) , c = 1.35860(3) , α=110.5300(10), β= 97.6140(10), γ= 93.7300(10) º, V= 1.80307(7) nm3, Dc= 1.404 g/cm3, Z=2, F(000)= 784. the final GooF = 1.047, R = 0.0398 and wR = 0.1038. The crystal structure of the title complex consists of one [Mn2(C12H8N2)4(C8H5O4)2]2+ cation,one uncoordinating o- phthalate anion (C8H4O4)2- and one uncoordinating water molecule. In [Mn2(C12H8N2)4(C8H5O4)2]2+, the central Mn(II) ion is coordinated by four nitrogen atoms and two oxygen atoms to give a distorted octahedral coordination geometry.The electrochemical property of the title complex was also studied.
Abstract：One dinuclear manganese(II) complex[Mn2(C12H8N2)4(C8H5O4)2](C8H4O4)·H2O has been synthesized with o- phthalic acid and 1,10–phenanthroline . The crystal structure was determined by X-ray diffraction. The crystal belongs to the triclinic system,space group P-1 with a =1.17767(3) , b =1.22292(2) , c = 1.35860(3) , α=110.5300(10), β= 97.6140(10), γ= 93.7300(10) º, V= 1.80307(7) nm3, Dc= 1.404 g/cm3, Z=2, F(000)= 784. the final GooF = 1.047, R = 0.0398 and wR = 0.1038. The crystal structure of the title complex consists of one [Mn2(C12H8N2)4(C8H5O4)2]2+ cation,one uncoordinating o- phthalate anion (C8H4O4)2- and one uncoordinating water molecule. In [Mn2(C12H8N2)4(C8H5O4)2]2+, the central Mn(II) ion is coordinated by four nitrogen atoms and two oxygen atoms to give a distorted octahedral coordination geometry.The electrochemical property of the title complex was also studied.
2011, Vol. 30 
